{(PMePh₂)4molybdenum(IV) hydride}

Base Information

Chemical Name:{(PMePh₂)4molybdenum(IV) hydride}
CAS No.:32109-07-2
Molecular Formula:C₅₂H₅₆MoP₄
Molecular Weight:900.852
Hs Code.:

{(PMePh<sub>2</sub>)4molybdenum(IV) hydride}

Synonyms:{(PMePh₂)4molybdenum(IV) hydride}

Suppliers and Price of {(PMePh₂)4molybdenum(IV) hydride}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {(PMePh₂)4molybdenum(IV) hydride}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {(PMePh₂)4molybdenum(IV) hydride}

There total 4 articles about {(PMePh₂)4molybdenum(IV) hydride} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 10241-05-1
molybdenum(V) chloride

: 1486-28-8
diphenyl(methyl)phosphine

: 32109-07-2
{(PMePh₂)4molybdenum(IV) hydride}

Guidance literature:: With hydrogen; magnesium; In tetrahydrofuran; addn. of MoCl5 to mixt. of Mg and phosphine in THF, stirred in an atmosphere of H2 for 6 h; sepd. from Mg residues, evapd., crystd. twice by dissolving in benzene and addn. of MeCN; elem. anal.;

Reference yield:

: cis-bis(PMePh₂)-bis(toluene-3,4-dithiolato)molybdenum(IV)*0.2SiO(CH₃)2

: 1486-28-8
diphenyl(methyl)phosphine

: 32109-07-2
{(PMePh₂)4molybdenum(IV) hydride}

: dihydrido(toluene-3,4-dithiolate)tris(PMePh₂)molybdenum

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; dissolving of Mo-compd. in THF (under N2), addn. of phosphine and LiAlH4, stirring for 14.5 h; solvent removal using vac., washing with hexanes and pentanes, monitored by (1)H NMR;

Reference yield:

: calcium borohydride

: 10241-05-1
molybdenum(V) chloride

: 1486-28-8
diphenyl(methyl)phosphine

: 32109-07-2
{(PMePh₂)4molybdenum(IV) hydride}

Guidance literature:: In not given; in inert atm. or in vac. from MoCl5, calcium borohydride and organic ligand as described by: (1) V. D. Makhaev, A. P. Borisov, N. G. Mozgina, G. N. Boiko, and K. N. Semenko, Izv. Akad. Nauk SSSR, Neorg. Mater., 14, 1726 (1978); (2): K. N. Semenko, V. D. Makhaev, A. P. Borisov, and G. N. Boiko, Koord. Khim., 4, 1550 (1978). (3): K. N. Ssemenko, V. D. Makhaev, and A. P. Borisov, Koord. Khim., 4, 147 (1978);