2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

Base Information

Chemical Name:2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone
CAS No.:115886-91-4
Molecular Formula:C₂₀H₂₅NO₈
Molecular Weight:407.42
Hs Code.:

Synonyms:2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

Suppliers and Price of 2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

There total 8 articles about 2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 121843-61-6
methyl 2-acetamido-4-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-xylo-hex-5-enopyranoside

: 121843-62-7
(R)-2-((1R,2S,5R,6S)-2-Acetoxy-6-acetylamino-5-hydroxy-3-oxo-cyclohexyloxy)-propionic acid benzyl ester

: 115886-91-4
2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

Guidance literature:: With sulfuric acid; mercury(II) sulfate; In 1,4-dioxane; at 80 ℃; for 2h; Yields of byproduct given;
DOI:10.1016/S0040-4020(01)97594-5

Reference yield:

: 121843-60-5
methyl 2-acetamido-4-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-2,6-dideoxy-6-iodo-α,β-D-glucopyranoside

: 115886-91-4
2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: AgF, pyridine

2: HgSO₄, 5 mM H₂SO₄ / dioxane; H₂O / 2 h / 80 °C

With pyridine; sulfuric acid; silver fluoride; mercury(II) sulfate; In 1,4-dioxane; water;
DOI:10.1021/jo00277a002

Reference yield:

: 121843-56-9
methyl-4,6-O-benzylidene-muramic acid

: 115886-91-4
2L-(2,4,5/3)-4-acetamido-2-O-acetyl-3-O-<(R)-1'-benzylcarboxyethyl>-5-hydroxy-cyclohexanone

Guidance literature:: Multi-step reaction with 7 steps

1: 84 percent / K₂CO₃ / dimethylformamide / Ambient temperature

2: 73 percent / aq. acetic acid / 1 h / Heating

3: pyridine / Ambient temperature

4: 4-dimethylaminopyridine / 18 h

5: 91 percent / KI / dimethylformamide / 1 h / 100 °C

6: 83 percent / AgF, pyridine / Ambient temperature

7: 52 percent / HgSO₄, aq. H₂SO₄ / dioxane / 2 h / 80 °C

With pyridine; dmap; sulfuric acid; silver fluoride; potassium carbonate; mercury(II) sulfate; acetic acid; potassium iodide; In 1,4-dioxane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)97594-5