2-METHYL-1-PHENYL-NAPHTHALENE

Base Information

• Chemical Name: 2-METHYL-1-PHENYL-NAPHTHALENE
• CAS No.: 29304-63-0
• Molecular Formula: C17H14
• Molecular Weight: 218.298
• Hs Code.: 2902909090
• Mol file: 29304-63-0.mol

Synonyms:2-Methyl-1-phenylnaphthalene

Chemical Property of 2-METHYL-1-PHENYL-NAPHTHALENE

Chemical Property:

• Vapor Pressure: 0.000116mmHg at 25°C
• Refractive Index: 1.635
• Boiling Point: 346.3°C at 760 mmHg
• Flash Point: 155.2°C
• PSA: 0.00000
• Density: 1.064g/cm³
• LogP: 4.81520

Purity/Quality:

99% ^*data from raw suppliers

2-METHYL-1-PHENYL-NAPHTHALENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-METHYL-1-PHENYL-NAPHTHALENE

There total 38 articles about 2-METHYL-1-PHENYL-NAPHTHALENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-bromo-2-methylnaphtalene (2586-62-1) + phenylboronic acid (98-80-6) → 2-methyl-1-phenylnaphthalene (29304-63-0)

Guidance literature:

With potassium phosphate; 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride; bis(η3-allyl-μ-chloropalladium(II)); In 1,4-dioxane; at 80 ℃; for 12h;

DOI:10.1002/adsc.200404015

Reference yield: 99.0%

1-bromo-2-methylnaphtalene (2586-62-1) + triallyl(phenyl)silane (2633-57-0) → 2-methyl-1-phenylnaphthalene (29304-63-0)

Guidance literature:

triallyl(phenyl)silane; With tetrabutyl ammonium fluoride; In water; dimethyl sulfoxide; at 20 ℃; for 1h;

1-bromo-2-methylnaphtalene; With tricyclohexylphosphine; palladium dichloride; In water; dimethyl sulfoxide; at 80 ℃; for 18h;

DOI:10.1002/adsc.200404188

Reference yield: 98.0%

1-chloro-2-methylnaphthalene (5859-45-0) + phenylboronic acid (98-80-6) → 2-methyl-1-phenylnaphthalene (29304-63-0)

Guidance literature:

With potassium phosphate; C₄₆H₅₂Cl₃N₃O₂Pd; In tetrahydrofuran; water; at 60 ℃; for 4h;

DOI:10.1021/acs.organomet.9b00230

upstream raw materials:

2-Methylnaphthalene

2-methyl-1-phenyl-3,4-dihydronaphthalene

dibenzoyl peroxide

iodobenzene

Downstream raw materials:

2-hydroxymethyl-1-phenylnaphthalene

1-phenylnaphthalene-2-carboxylic acid

benzo[c]fluorene

2-Bromomethyl-1-phenyl-naphthalene