2,6-Dimethyloct-7-ene-2,6-diol

Base Information

• Chemical Name: 2,6-Dimethyloct-7-ene-2,6-diol
• CAS No.: 29210-77-3
• Deprecated CAS: 57784-11-9,98206-62-3
• Molecular Formula: C10H20 O2
• Molecular Weight: 172.268
• Hs Code.: 2905399090
• European Community (EC) Number: 249-511-2
• UNII: F7S8KYN9GG
• DSSTox Substance ID: DTXSID10880698
• Nikkaji Number: J250.799D
• Metabolomics Workbench ID: 49284
• Mol file: 29210-77-3.mol

Synonyms:2,6-Dimethyloct-7-ene-2,6-diol;7-Octene-2,6-diol, 2,6-dimethyl-;29210-77-3;6,7-Dihydro-7-hydroxylinalool;2,6-Dimethyl-7-octene-2,6-diol;F7S8KYN9GG;EINECS 249-511-2;EINECS 260-961-9;cis-linalool hydrate;7-Octene-2,6-diol;UNII-F7S8KYN9GG;3-HYDROXYDIHYDROMYRCENOL;7-Hydroxy-6,7-dihydrolinalool;SCHEMBL4118679;DTXSID10880698;CHEBI:179552;3,7-dimethyl-1-octen-3,7-diol;2,6-Dimethyl-7-octen-2,6-diol;2,6-Dimethyloct-7-en-2,6-diol;3,7-Dimethyl-1-octene-3,7-diol;3,7-Dimethyloct-1-ene-3,7-diol;1-Octen-3,7-diol, 3,7-dimethyl;AKOS015841432;3,7-Dimethyl-3,7-dihydroxyoct-1-ene;(1)-2,6-Dimethyloct-7-ene-2,6-diol;(+-)-2,6-dimethyloct-7-ene-2,6-diol

Chemical Property of 2,6-Dimethyloct-7-ene-2,6-diol

Chemical Property:

• Boiling Point: 283.9°Cat760mmHg
• Flash Point: 129.4°C
• PSA: 40.46000
• Density: 0.937g/cm³
• LogP: 1.86460
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 172.146329876
• Heavy Atom Count: 12
• Complexity: 152

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(CCCC(C)(C=C)O)O

Technology Process of 2,6-Dimethyloct-7-ene-2,6-diol

There total 9 articles about 2,6-Dimethyloct-7-ene-2,6-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-dimethyloct-7-yne-2,6-diol (29210-76-2) → 2,6-dimethyloct-7-ene-2,6-diol (29210-77-3,57784-11-9)

Guidance literature:

With palladium on carbon poisoned with lead; hydrogen; In toluene; at 34 - 40 ℃; for 7.5h; under 75.0075 - 150.015 Torr; Inert atmosphere; Large scale;

Reference yield:

1-(3,4-epoxy-4-methylpentyl)-1-methylallyl acetate (41610-76-8) → 2,6-dimethyloct-7-ene-2,6-diol (29210-77-3,57784-11-9)

Guidance literature:

With lithium aluminium tetrahydride;

DOI:10.1021/jf970987x

Reference yield:

linalool acetate (115-95-7) → 2,6-dimethyloct-7-ene-2,6-diol (29210-77-3,57784-11-9)

Guidance literature:

Multi-step reaction with 2 steps

1: MCPBA

2: LiAlH₄

With lithium aluminium tetrahydride; 3-chloro-benzenecarboperoxoic acid;

DOI:10.1021/jf970987x

upstream raw materials:

2,6-dimethyl-6-tetrahydropyran-2-yloxy-oct-7-en-2-ol

1-(3,4-epoxy-4-methylpentyl)-1-methylallyl acetate

3,7-dimethyl-2E,6-octadien-1-yl acetate

linalool acetate

Downstream raw materials:

2-vinyl-2,6,6-trimethyl-3,4,5,6-tetrahydro-2H-pyran

(E/Z)-5,9-dimethyldeca-4,8-dienal

(E/Z)-5,9-dimethyldeca-4,9-dienal