5,10,15-triphenyl(2⁽²⁾-oxo-benzo[2⁽³⁾,2⁽⁴⁾]cyclohexa[a,b]porphinato^(2-))copper(II)

Base Information

• Chemical Name: 5,10,15-triphenyl(2⁽²⁾-oxo-benzo[2⁽³⁾,2⁽⁴⁾]cyclohexa[a,b]porphinato^(2-))copper(II)
• CAS No.: 75923-80-7
• Molecular Formula: C₄₅H₂₆CuN₄O
• Molecular Weight: 702.274

Synonyms:5,10,15-triphenyl(2⁽²⁾-oxo-benzo[2⁽³⁾,2⁽⁴⁾]cyclohexa[a,b]porphinato^(2-))copper(II)

Chemical Property of 5,10,15-triphenyl(2⁽²⁾-oxo-benzo[2⁽³⁾,2⁽⁴⁾]cyclohexa[a,b]porphinato^(2-))copper(II)

Chemical Property:

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Technology Process of 5,10,15-triphenyl(2⁽²⁾-oxo-benzo[2⁽³⁾,2⁽⁴⁾]cyclohexa[a,b]porphinato^(2-))copper(II)

There total 2 articles about 5,10,15-triphenyl(2⁽²⁾-oxo-benzo[2⁽³⁾,2⁽⁴⁾]cyclohexa[a,b]porphinato^(2-))copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

β-formyl-5,10,15,20-tetrakis(phenyl)porphyrin copper(II) (71763-49-0) → 5,10,15-triphenyl(2(2)-oxo-benzo[2(3),2(4)]cyclohexa[a,b]porphinato(2-))copper(II) (75923-80-7)

Guidance literature:

With TsOH*H₂O; chloranil; In 1,2-dichloro-ethane; benzene; Cu compd. added to soln. of TsOH*H2O and chloranil in 1,2-dichloroethaneand benzene; refluxed for 1.5 h; org. phase washed with satd. aq. NaHCO3 and water; dried (Na2SO4); chromd. (alumina, 1,2-dichloroethane); green fraction concd.; crystd. (CH2Cl2-MeOH);

DOI:10.1021/ja017531n

Reference yield:

(tetraphenylporphyrin)copper(II) (14172-91-9) → 5,10,15-triphenyl(2(2)-oxo-benzo[2(3),2(4)]cyclohexa[a,b]porphinato(2-))copper(II) (75923-80-7)

Guidance literature:

Multi-step reaction with 2 steps

1: POCl₃ / chloroform

2: H₂O / trifluoroacetic acid

With POCl₃; H₂O; In chloroform; trifluoroacetic acid;

DOI:10.1016/S0020-1693(00)80132-2

Reference yield: 88.0%

4-amino-1,2,4-triazole (584-13-4) + 5,10,15-triphenyl(2(2)-oxo-benzo[2(3),2(4)]cyclohexa[a,b]porphinato(2-))copper(II) (75923-80-7) → (C6H5)3(NH2)C27H10N4OCu (437653-47-9)

Guidance literature:

With NaOH; In ethanol; toluene; EtOH, 4-amino-4H-1,2,4-triazole (11.7 equiv.) and NaOH added to toluene soln. of Cu complex; refluxed for 1 h; cooled; washed with water; dried (Na2SO4); filtered (silica gel, CH2Cl2); crystd. (CH2Cl2-MeOH); elem. anal.;

DOI:10.1021/ja017531n

upstream raw materials:

β-formyl-5,10,15,20-tetrakis(phenyl)porphyrin copper(II)

(tetraphenylporphyrin)copper(II)

Downstream raw materials:

(C₆H₅)3(NH₂)C₂₇H₁₀N₄OCu

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