1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]

Base Information

Chemical Name:1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]
CAS No.:299205-77-9
Molecular Formula:C₄₆H₆₂O₈S₂
Molecular Weight:807.125
Hs Code.:

Synonyms:1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]

Chemical Property:

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Technology Process of 1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]

There total 7 articles about 1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 98-59-9
p-toluenesulfonyl chloride

: 299205-73-5
1,1'-(1,6-hexanediyl)bis[5-(6-hydroxyhexyl)-2-methoxybenzene]

: 299205-77-9
1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]

Guidance literature:: With pyridine; In dichloromethane;
DOI:10.1021/jo0003044

Reference yield:

: 629-11-8
1,6-hexanediol

: 299205-77-9
1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]

Guidance literature:: Multi-step reaction with 5 steps

1.1: 60 percent / pyridine / CH₂Cl₂ / 3.67 h / -5 - 0 °C

2.1: 86 percent / P₂O₅ / various solvent(s) / 0.5 h

3.1: Mg / tetrahydrofuran / Heating

3.2: 73 percent / LiBr; CuBr*SMe₂; PhSLi / tetrahydrofuran; hexamethylphosphoric acid triamide / Heating

4.1: 98 percent / aq. HCl / methanol / Heating

5.1: 93 percent / pyridine / CH₂Cl₂

With pyridine; hydrogenchloride; phosphorus pentoxide; magnesium; In tetrahydrofuran; methanol; dichloromethane; 1.1: Tosylation / 2.1: Substitution / 3.1: Metallation / 3.2: Substitution / 4.1: Hydrolysis / 5.1: Tosylation;
DOI:10.1021/jo0003044

Reference yield:

: 75351-33-6
(6-hydroxyhexyl)tosylate

: 299205-77-9
1,1'-(1,6-hexanediyl)bis[5-(6-(4-methylbenzenesulfonyloxy)hexyl)-2-methoxybenzene]

Guidance literature:: Multi-step reaction with 4 steps

1.1: 86 percent / P₂O₅ / various solvent(s) / 0.5 h

2.1: Mg / tetrahydrofuran / Heating

2.2: 73 percent / LiBr; CuBr*SMe₂; PhSLi / tetrahydrofuran; hexamethylphosphoric acid triamide / Heating

3.1: 98 percent / aq. HCl / methanol / Heating

4.1: 93 percent / pyridine / CH₂Cl₂

With pyridine; hydrogenchloride; phosphorus pentoxide; magnesium; In tetrahydrofuran; methanol; dichloromethane; 1.1: Substitution / 2.1: Metallation / 2.2: Substitution / 3.1: Hydrolysis / 4.1: Tosylation;
DOI:10.1021/jo0003044