methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside

Base Information

Chemical Name:methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside
CAS No.:1520095-06-0
Molecular Formula:C₆₃H₆₇O₁₆P
Molecular Weight:1111.19
Hs Code.:

Synonyms:methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside

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Chemical Property of methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside

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Technology Process of methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside

There total 1 articles about methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1520094-95-4
methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-O-benzoyl-4-O-dibenzyloxyphosphoryl-6,7-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-L-glycero-α-D-manno-heptopyranoside

: 1520095-06-0
methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside

Guidance literature:: With triethylamine tris(hydrogen fluoride); In dichloromethane; at 0 ℃; regioselective reaction;
DOI:10.1021/jo402312x

Reference yield: 95.0%

: 1520095-06-0
methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside

: 121-44-8
triethylamine

: 1520095-08-2
methyl (α-D-glucopyranosyl)-(1→3)-2-O-benzoyl-L-glycero-α-D-manno-heptopyranoside 4-O-phosphate triethylammonium salt

Guidance literature:: methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside; With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 7h;

triethylamine; In methanol;
DOI:10.1021/jo402312x

Reference yield:

: 1520095-06-0
methyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2-Obenzoyl-4-O-dibenzyloxyphosphoryl-L-glycero-α-D-manno-heptopyranoside

: methyl (L-glycero-α-D-manno-heptopyranosyl)-(1→7)-L-glycero-α-D-manno-heptopyranoside 4-O-phosphate monosodium salt

Guidance literature:: Multi-step reaction with 2 steps

1: palladium 10% on activated carbon; hydrogen / methanol / 7 h / 20 °C

2: sodium methylate / methanol / 14 h / 20 °C

With palladium 10% on activated carbon; hydrogen; sodium methylate; In methanol;
DOI:10.1021/jo402312x