C₅₂H₅₂N₄Zn

Base Information

• Chemical Name: C₅₂H₅₂N₄Zn
• CAS No.: 207971-12-8
• Molecular Formula: C₅₂H₅₂N₄Zn
• Molecular Weight: 798.402
• Mol file: 207971-12-8.mol

Synonyms:C₅₂H₅₂N₄Zn

Chemical Property of C₅₂H₅₂N₄Zn

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₂H₅₂N₄Zn

There total 2 articles about C₅₂H₅₂N₄Zn which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

3-(trimethylsilyl)prop-2-yn-1-al (2975-46-4) + zinc(II) acetate dihydrate (5970-45-6) + (3,5-di-tert-butylphenyl)di(pyrrol-2-yl)methane (181762-72-1) → (C20H8N4Zn)(C6H3(C(CH3)3)2)2(CCH)2 (207971-12-8)

Guidance literature:

With BF₃*OEt₂; 2,3-dichloro-5,6-dicyano-p-benzoquinone; Bu₄NF; In dichloromethane; addn. of the aldehyde and BF3*OEt2 to the dipyrromethane in CH2Cl2, addn. of DDQ, addn. of Zn(OAc)2, addn. of Bu4NF;

DOI:10.1002/(SICI)1521-3773(19980420)37:7<986::AID-ANIE986>3.0.CO;2-D

Reference yield:

C70H92N4Si2Zn (438544-25-3) → (C20H8N4Zn)(C6H3(C(CH3)3)2)2(CCH)2 (207971-12-8)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 25 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/b919645e

Reference yield: 87.0%

(C20H8N4Zn)(C6H3(C(CH3)3)2)2(CCH)2 (207971-12-8) + dihexyl 6-bromoazulene-1,3-dicarboxylate (501123-88-2) → ((C(CH3)3)2C6H3)2(C2C10H6CO2C6H13)(C10H5(CO2C6H13)2C2)C20H8N4Zn (936631-11-7)

Guidance literature:

With Et₃N; catalyst:Pd(PPh₃)4, CuI; TIPSCl; In tetrahydrofuran; reacted in THF catalyzed by Pd(PPh3)4, CuI in the presence of Et3N and TIPSCl through intermediates with CC-TIPS groups;

DOI:10.1039/b704986b

upstream raw materials:

3-(trimethylsilyl)prop-2-yn-1-al

zinc(II) acetate dihydrate

(3,5-di-tert-butylphenyl)di(pyrrol-2-yl)methane

C₇₀H₉₂N₄Si₂Zn

Downstream raw materials:

[Zn(C₈₀H₆₆I₂N₄)]

((C(CH₃)3)2C₆H₃)2(C₁₀H₆CO₂C₆H₁₃C₂)2C₂₀H₈N₄Zn

((C(CH₃)3)2C₆H₃)2(C₂C₁₀H₆CO₂C₆H₁₃)(C₁₀H₅(CO₂C₆H₁₃)2C₂)C₂₀H₈N₄Zn

((C(CH₃)3)2C₆H₃)2(C₁₀H₅(CO₂C₆H₁₃)2C₂)2C₂₀H₈N₄Zn