(1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol

Base Information

Chemical Name:(1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol
CAS No.:130249-24-0
Molecular Formula:C₂₁H₃₆O₄S₄Si
Molecular Weight:508.864
Hs Code.:

Synonyms:(1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol

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Technology Process of (1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol

There total 1 articles about (1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 34410-04-3
2-lithio-2-trimethylsilyl-1,3-dithiane

: 130249-23-9
(1S,4R,6S)-4-Hydroxy-4-(2-methyl-[1,3]dioxolan-2-yl)-7-oxa-bicyclo[4.1.0]heptan-2-one

: 130249-24-0
(1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol

Guidance literature:: In tetrahydrofuran; at -78 ℃; for 1h;
DOI:10.1021/jo00308a007

Reference yield:

: 130249-24-0
(1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol

: 130249-25-1
(1S,3S,4S)-4-[1,3]Dithian-2-yl-5-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-cyclohexane-1,3-diol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 23 ℃;
DOI:10.1021/jo00308a007

Reference yield:

: 130249-24-0
(1S,4S,5S)-4-[1,3]Dithian-2-yl-3-[1,3]dithian-2-ylidene-1-(2-methyl-[1,3]dioxolan-2-yl)-5-trimethylsilanyloxy-cyclohexanol

: 130249-38-6,130322-59-7
(2S,3S,5R)-1-Bromo-2-dimethoxymethyl-3,5-dihydroxy-5-(2-methyl-[1,3]dioxolan-2-yl)-cyclohexanecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: tetrabutylammonium fluoride / tetrahydrofuran / 23 °C

2: CH₂Cl₂ / 0 °C

3: 81 percent / Br₂, CaCO₃ / H₂O; methanol / 0.5 h / 0 °C

With tetrabutyl ammonium fluoride; bromine; calcium carbonate; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/jo00308a007