1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone

Base Information

Chemical Name:1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone
CAS No.:861996-60-3
Molecular Formula:C₂₃H₃₂O₂
Molecular Weight:340.506
Hs Code.:

Synonyms:1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone

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Chemical Property of 1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone

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Technology Process of 1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone

There total 1 articles about 1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 2398-37-0
3-methoxyphenyl bromide

: 434284-14-7
N-methoxy-N-methyl-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylenedecahydronaphthalen-1-yl)acetamide

: 861996-60-3
1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone

Guidance literature:: 3-methoxyphenyl bromide; With n-butyllithium; In tetrahydrofuran; at -78 ℃;

N-methoxy-N-methyl-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylenedecahydronaphthalen-1-yl)acetamide; In tetrahydrofuran; at -78 ℃; for 0.333333h;
DOI:10.1002/chem.200401220

Reference yield: 88.0%

: 861996-60-3
1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone

: 1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanol

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride; In methanol; at 0 ℃; for 1h;
DOI:10.1002/chem.200401220

Reference yield:

: 861996-60-3
1-(3-Methoxy-phenyl)-2-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethanone

: 861996-68-1
{(1S,2S,4aS,8aR)-1-[2-(3-Methoxy-phenyl)-ethyl]-5,5,8a-trimethyl-decahydro-naphthalen-2-yl}-methanol

Guidance literature:: Multi-step reaction with 4 steps

1.1: 88 percent / NaBH₄; CeCl₃*7H₂O / methanol / 1 h / 0 °C

2.1: 80 mg / CH₂Cl₂

3.1: 62 mg / Bu₃SnH; AIBN / toluene / Heating

4.1: B₂H₆*Me₂S / tetrahydrofuran; various solvent(s) / 0 - 20 °C

4.2: 61 percent / aq. H₂O₂; NaOH / tetrahydrofuran; various solvent(s) / 1 h / 0 °C

With sodium tetrahydroborate; cerium(III) chloride; 2,2'-azobis(isobutyronitrile); diborane-dimethylsulfide complex; tri-n-butyl-tin hydride; In tetrahydrofuran; methanol; dichloromethane; toluene; 1.1: Luche reduction;
DOI:10.1002/chem.200401220