N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide

Base Information

• Chemical Name: N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide
• CAS No.: 308291-71-6
• Molecular Formula: C₂₁H₁₈N₂O₃S
• Molecular Weight: 378.452
• Mol file: 308291-71-6.mol

Synonyms:N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide

Chemical Property of N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide

There total 3 articles about N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

N-[1-(4-Hydroxy-2,6-dimethyl-phenylamino)-1-phenyl-meth-(E)-ylidene]-benzenesulfonamide → N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide (308291-71-6)

Guidance literature:

With lead(IV) acetate; In acetic acid;

DOI:10.1023/A:1012430601142

Reference yield:

3,5-dimethyl-4-aminophenol (3096-70-6) → N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide (308291-71-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / NaOAc / dimethylformamide; acetic acid / 0.5 h

2: 61 percent / Pb(OAc)4 / acetic acid

With lead(IV) acetate; sodium acetate; In acetic acid; N,N-dimethyl-formamide;

DOI:10.1023/A:1012430601142

Reference yield:

N-phenylsulfonylbenzimidoyl chloride (4513-25-1) → N-(2,6-dimethyl-4-oxocyclohexa-2,5-dienylidene)-N'-(phenylsulfonyl)benzimidamide (308291-71-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / NaOAc / dimethylformamide; acetic acid / 0.5 h

2: 61 percent / Pb(OAc)4 / acetic acid

With lead(IV) acetate; sodium acetate; In acetic acid; N,N-dimethyl-formamide;

DOI:10.1023/A:1012430601142

upstream raw materials:

3,5-dimethyl-4-aminophenol

N-phenylsulfonylbenzimidoyl chloride

Downstream raw materials:

3,5-dimethyl-4-[(phenyl)(phenylsulfonylimino)methylamino]phenyl 4-methylbenzenesulfonate

N-[4-hydroxy-2,6-dimethyl-3-(4-methylphenylsulfonyl)phenyl]-N'-(phenylsulfonyl)benzimidamide

N-[1-(3,5-Dibromo-4-hydroxy-2,6-dimethyl-phenylamino)-1-phenyl-meth-(Z)-ylidene]-benzenesulfonamide

N-[1-(3,5-Dichloro-4-hydroxy-2,6-dimethyl-phenylamino)-1-phenyl-meth-(Z)-ylidene]-benzenesulfonamide