5-NITRO-1-PENTENE

Base Information

• Chemical Name: 5-NITRO-1-PENTENE
• CAS No.: 23542-51-0
• Molecular Formula: C5H9 N O2
• Molecular Weight: 115.132
• Hs Code.: 2904209090
• Mol file: 23542-51-0.mol

Synonyms:1-Nitropent-4-ene;5-Nitropent-1-ene

Chemical Property of 5-NITRO-1-PENTENE

Chemical Property:

• Vapor Pressure: 2.66mmHg at 25°C
• Refractive Index: n20/D 1.44(lit.)
• Boiling Point: 82 °C32 mm Hg(lit.)
• PKA: 8?+-.0.29(Predicted)
• Flash Point: 155 °F
• PSA: 45.82000
• Density: 1.007 g/mL at 25 °C(lit.)
• LogP: 1.75250
• Storage Temp.: 2-8°C

Purity/Quality:

99.90% ^*data from raw suppliers

5-NITRO-1-PENTENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 25-43
• Safety Statements: 45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-NITRO-1-PENTENE

There total 2 articles about 5-NITRO-1-PENTENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

1-bromo-1-nitropent-4-ene (133367-89-2) → 5-nitropent-1-ene (23542-51-0)

Guidance literature:

2,2'-azobis(isobutyronitrile); In toluene; at 40 ℃; Mechanism; Irradiation;

Reference yield: 40.0%

bromopentene (1119-51-3) → 5-nitropent-1-ene (23542-51-0)

Guidance literature:

With urea; sodium nitrite; In dimethyl sulfoxide; at 0 - 20 ℃; for 6h;

DOI:10.1002/anie.201706401

Reference yield: 92.0%

5-nitropent-1-ene (23542-51-0) + phenylacetylene (536-74-3) → 3-(but-2-enyl)-6-phenylisoxazole

Guidance literature:

With dmap; 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride; In acetonitrile; at 80 ℃; for 0.05h; microwave irradiation;

DOI:10.1016/S0040-4020(03)00859-7

upstream raw materials:

bromopentene

1-bromo-1-nitropent-4-ene

Downstream raw materials:

3-allylindole

Refernces

• 1、 Cavanagh, Craig W.,Aukland, Miles H.,Laurent, Quentin,Hennessy, Alan,Procter, David J.. "Iron-mediated oxidative C-H coupling of arenes and alkenes directed by sulfur: An expedient route to dihydrobenzofurans". supporting information. p. 5286 - 5292. Retrieved 2016/07/06.
• 2、 Bowman, W. Russell,Crosby, David,Westlake, Paul J.. "Reduction of Substituted Nitro Compounds with Tri-n-butyltin Hydride". . p. 73 - 80. Retrieved 2007/10/02.