methyl (Z)-2-benzenesulfonyl-4-(2'-acetoxy-3'-cyclohexen-1'-yl)butanoate

Base Information

Chemical Name:methyl (Z)-2-benzenesulfonyl-4-(2'-acetoxy-3'-cyclohexen-1'-yl)butanoate
CAS No.:63294-62-2
Molecular Formula:C₁₉H₂₄O₆S
Molecular Weight:380.462
Hs Code.:

Synonyms:methyl (Z)-2-benzenesulfonyl-4-(2'-acetoxy-3'-cyclohexen-1'-yl)butanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (Z)-2-benzenesulfonyl-4-(2'-acetoxy-3'-cyclohexen-1'-yl)butanoate

Chemical Property:

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Technology Process of methyl (Z)-2-benzenesulfonyl-4-(2'-acetoxy-3'-cyclohexen-1'-yl)butanoate

There total 16 articles about methyl (Z)-2-benzenesulfonyl-4-(2'-acetoxy-3'-cyclohexen-1'-yl)butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 60729-65-9
sodim salt of methyl benzenesulfonylacetate

: 63294-71-3
Acetic acid (1S,6S)-6-[2-(toluene-4-sulfonyloxy)-ethyl]-cyclohex-2-enyl ester

: 63294-62-2
methyl (Z)-2-benzenesulfonyl-4-(2'-acetoxy-3'-cyclohexen-1'-yl)butanoate

Guidance literature:: In N,N,N,N,N,N-hexamethylphosphoric triamide; at 50 ℃; for 4h;
DOI:10.1021/ja00534a030

Reference yield:

: 63294-67-7
Acetic acid 6-(2-oxo-ethyl)-cyclohex-2-enyl ester

: 63294-62-2
3-acetoxy-4-(3-phenylsulfonyl-3-methoxycarboxy-propyl)-cyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1: sodium borohydride / ethanol / 0 °C

2: pyridine / 0 °C

3: hexamethylphosphoric acid triamide / 50 °C

With pyridine; sodium tetrahydroborate; In N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol;
DOI:10.1021/ja00534a030

Reference yield:

: 52866-38-3,52866-39-4,61088-60-6
(+/-)-cis-2-acetoxy-cyclohex-3-enecarbaldehyde

: 63294-62-2
3-acetoxy-4-(3-phenylsulfonyl-3-methoxycarboxy-propyl)-cyclohexene

Guidance literature:: Multi-step reaction with 9 steps

1: 88 percent / diethyl ether; hexane / 0.5 h / 0 °C

2: aq. NaOH / tetrahydrofuran; ethanol / Ambient temperature

3: 62 percent / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / Ambient temperature

4: LiAlH₄ / diethyl ether / 0 °C

5: 66 percent / NaH / 60 °C

6: oxalic acid / tetrahydrofuran; H₂O / Ambient temperature

7: sodium borohydride / ethanol / 0 °C

8: pyridine / 0 °C

9: hexamethylphosphoric acid triamide / 50 °C

With pyridine; sodium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; sodium acetate; oxalic acid; sodium hydride; pyridinium chlorochromate; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; ethanol; hexane; dichloromethane; water;
DOI:10.1021/ja00534a030