5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

Base Information

Chemical Name:5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole
CAS No.:116513-12-3
Molecular Formula:C₂₁H₂₂O₅
Molecular Weight:354.403
Hs Code.:

Synonyms:5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

Suppliers and Price of 5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Hazard Codes:

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Technology Process of 5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

There total 9 articles about 5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (2S,3S)-3-((E)-3-Benzo[1,3]dioxol-5-yl-allyloxy)-butane-1,2,4-triol

: 116513-12-3
5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

Guidance literature:: Multi-step reaction with 12 steps

4: IO₄^(1-)

5: 4-N,N-dimethylaminopyridine / CH₂Cl₂ / 0 deg C to RT

6: MgCl₂ / N,N-dimethyl-acetamide; H₂O / Heating

7: oxidodiperoxy(pyridine)(hexamethylphosphoric triamide)molybdenum, lithium hexamethyldisilazide

8: NaBH₄

9: NaIO₄

10: NaBH₄

12: n-butyllithium

With dmap; sodium tetrahydroborate; sodium periodate; n-butyllithium; MoO₅*pyridine*HMPA; periodate; magnesium chloride; lithium hexamethyldisilazane; In dichloromethane; N,N-dimethyl acetamide; water;
DOI:10.1039/c39880000189

Reference yield:

: (S)-2-((E)-3-Benzo[1,3]dioxol-5-yl-allyloxy)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol

: 116513-12-3
5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

Guidance literature:: Multi-step reaction with 11 steps

3: IO₄^(1-)

4: 4-N,N-dimethylaminopyridine / CH₂Cl₂ / 0 deg C to RT

5: MgCl₂ / N,N-dimethyl-acetamide; H₂O / Heating

6: oxidodiperoxy(pyridine)(hexamethylphosphoric triamide)molybdenum, lithium hexamethyldisilazide

7: NaBH₄

8: NaIO₄

9: NaBH₄

11: n-butyllithium

With dmap; sodium tetrahydroborate; sodium periodate; n-butyllithium; MoO₅*pyridine*HMPA; periodate; magnesium chloride; lithium hexamethyldisilazane; In dichloromethane; N,N-dimethyl acetamide; water;
DOI:10.1039/c39880000189

Reference yield:

: 5-{(E)-3-[(S)-2-Benzyloxy-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethoxy]-propenyl}-benzo[1,3]dioxole

: 116513-12-3
5-((1R,3aS,4R,6aS)-4-Benzyloxymethyl-tetrahydro-furo[3,4-c]furan-1-yl)-benzo[1,3]dioxole

Guidance literature:: Multi-step reaction with 10 steps

2: IO₄^(1-)

3: 4-N,N-dimethylaminopyridine / CH₂Cl₂ / 0 deg C to RT

4: MgCl₂ / N,N-dimethyl-acetamide; H₂O / Heating

5: oxidodiperoxy(pyridine)(hexamethylphosphoric triamide)molybdenum, lithium hexamethyldisilazide

6: NaBH₄

7: NaIO₄

8: NaBH₄

10: n-butyllithium

With dmap; sodium tetrahydroborate; sodium periodate; n-butyllithium; MoO₅*pyridine*HMPA; periodate; magnesium chloride; lithium hexamethyldisilazane; In dichloromethane; N,N-dimethyl acetamide; water;
DOI:10.1039/c39880000189