(S)-(+)-1-naphthylphenylphosphinoferrocene

Base Information

Chemical Name:(S)-(+)-1-naphthylphenylphosphinoferrocene
CAS No.:279243-51-5
Molecular Formula:C₂₆H₂₁FeP
Molecular Weight:420.274
Hs Code.:

Synonyms:(S)-(+)-1-naphthylphenylphosphinoferrocene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-(+)-1-naphthylphenylphosphinoferrocene

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Technology Process of (S)-(+)-1-naphthylphenylphosphinoferrocene

There total 1 articles about (S)-(+)-1-naphthylphenylphosphinoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 102-54-5,55404-68-7
ferrocene

: 199396-00-4,202756-08-9,202756-09-0
methyl (R)-(-)-(1-naphthyl)phenylphosphinite borane complex

: 279243-51-5
(S)-(+)-1-naphthylphenylphosphinoferrocene

Guidance literature:: With tert-butyllithium; diethylamine; In tetrahydrofuran; diethylamine; pentane; under Ar atm. soln. tert-BuLi in pentane was added at 0°C to ferrocene in THF and stirred for 15 min, soln. was added at -40°C tosoln. phosphinite borane in THF, allowed to warm for 12 h, H2O was added, soln. was evapd., Et2NH was added; after stirring overnight at room temp., solvent was removed, purified by chromy. (SiO2; hexane/CH2Cl2) and recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/om991013s