(1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde

Base Information

• Chemical Name: (1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde
• CAS No.: 1021877-55-3
• Molecular Formula: C₃₀H₄₆O₃Si₂
• Molecular Weight: 510.864
• Mol file: 1021877-55-3.mol

Synonyms:(1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde

Chemical Property of (1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde

There total 1 articles about (1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

{(1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentyl}-methanol (1021877-54-2) → (1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde (1021877-55-3)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1016/j.tet.2008.01.134

Reference yield: 88.0%

(1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde (1021877-55-3) → (1R,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde (1021877-56-4)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; for 4h;

DOI:10.1016/j.tet.2008.01.134

upstream raw materials:

{(1S,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentyl}-methanol

Downstream raw materials:

(1R,2R,4S)-4-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-cyclopentanecarbaldehyde