Rh(2,6-Me₂C₆H₃)(2,5-norbornadiene)(PPh₃)

Base Information

• Chemical Name: Rh(2,6-Me₂C₆H₃)(2,5-norbornadiene)(PPh₃)
• CAS No.: 309759-98-6
• Molecular Formula: C₃₃H₃₂PRh
• Molecular Weight: 562.496
• Mol file: 309759-98-6.mol

Synonyms:Rh(2,6-Me₂C₆H₃)(2,5-norbornadiene)(PPh₃)

Chemical Property of Rh(2,6-Me₂C₆H₃)(2,5-norbornadiene)(PPh₃)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Rh(2,6-Me₂C₆H₃)(2,5-norbornadiene)(PPh₃)

There total 2 articles about Rh(2,6-Me₂C₆H₃)(2,5-norbornadiene)(PPh₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

di-μ-chlorobis(norbornadiene)dirhodium(I) + 2-Bromo-m-xylene (576-22-7) + triphenylphosphine (603-35-0) → Rh(2,6-Me2C6H3)(2,5-norbornadiene)(PPh3) (309759-98-6)

Guidance literature:

With n-BuLi; In tetrahydrofuran; diethyl ether; hexane; (Ar); soln. of BuLi in hexane was slowly added to soln. of aryl bromide in Et2O at -78°C; mixt. was stirred for 10 min and warmed to roomtemp.; soln. of Rh complex and PPh3 in THF was added at room temp.; sti rred for 30 min; quenched with MeOH; solvent removed (vac.); chromd. (alumina, C6H6); concd.; recrystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1021/om0509692

Reference yield: 96.0%

di-μ-chlorobis(norbornadiene)dirhodium(I) + 2,6-xylyllithium (63509-96-6) + triphenylphosphine (603-35-0) → Rh(2,6-Me2C6H3)(2,5-norbornadiene)(PPh3) (309759-98-6)

Guidance literature:

In tetrahydrofuran;

DOI:10.1021/om0005809

Reference yield:

Rh(2,6-Me2C6H3)(2,5-norbornadiene)(PPh3) (309759-98-6) + 4-(hexyloxycarbonyl)phenyl isocyanide (289616-89-3) → (Ph3P)Rh(CNC6H4C(O)O(n-hexyl))2(CNC6H4C(O)O(n-hexyl))(x)(2,6-Me2C6H4)

Guidance literature:

In benzene-d6; (Ar); Rh complex was treated with isocyanide in C6D6 at room temp.; NMR monitoring; not isolated;

DOI:10.1021/om0509692

upstream raw materials:

2-Bromo-m-xylene

triphenylphosphine

2,6-xylyllithium