C₈H₁₃BrO₄

Base Information

• Chemical Name: C₈H₁₃BrO₄
• CAS No.: 1572455-07-2
• Molecular Formula: C₈H₁₃BrO₄
• Molecular Weight: 253.093
• Mol file: 1572455-07-2.mol

Synonyms:C₈H₁₃BrO₄

Chemical Property of C₈H₁₃BrO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₈H₁₃BrO₄

There total 4 articles about C₈H₁₃BrO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

C11H17BrO4 (1572455-04-9) → C8H13BrO4 (1572455-07-2)

Guidance literature:

With acetic acid; In water; at 70 ℃; for 14h;

DOI:10.1021/jo500210k

Reference yield:

(3aS,7aS)-4-bromo-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole (130669-75-9) → C8H13BrO4 (1572455-07-2)

Guidance literature:

Multi-step reaction with 3 steps

1.1: osmium(VIII) oxide / water; acetone / 8 h / 18 °C

2.1: sodium hydride / mineral oil; tetrahydrofuran / 0.5 h / 0 °C

2.2: 1 h / 18 °C

3.1: acetic acid / water / 14 h / 70 °C

With osmium(VIII) oxide; sodium hydride; acetic acid; In tetrahydrofuran; water; acetone; mineral oil;

DOI:10.1021/jo500210k

Reference yield:

(3aS,4R,5R,7aS)-7-bromo-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxole-4,5-diol (137501-12-3,130669-72-6) → C8H13BrO4 (1572455-07-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium hydride / mineral oil; tetrahydrofuran / 0.5 h / 0 °C

1.2: 1 h / 18 °C

2.1: acetic acid / water / 14 h / 70 °C

With sodium hydride; acetic acid; In tetrahydrofuran; water; mineral oil;

DOI:10.1021/jo500210k

upstream raw materials:

(3aS,7aS)-4-bromo-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole

(3aS,4R,5R,7aS)-7-bromo-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxole-4,5-diol

C₁₁H₁₇BrO₄

cis-(1S,2S)-1,2-dihydroxy-3-bromocyclohexa-3,5-diene

Downstream raw materials:

C₁₆H₂₁BrO₅

C₂₂H₂₆O₆

C₂₂H₂₄O₅

C₂₂H₂₄O₆