5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole

Base Information

Chemical Name:5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole
CAS No.:861997-79-7
Molecular Formula:C₂₆H₄₂N₄O₄S
Molecular Weight:506.71
Hs Code.:

5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1<i>H</i>-tetrazole

Synonyms:5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole

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Chemical Property of 5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole

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Technology Process of 5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole

There total 10 articles about 5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 861997-78-6
1-(1-phenyl-1H-tetrazole-5-sulfonyl)-heptadecan-8-one

: 7381-30-8
2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane

: 861997-79-7
5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -5 ℃; for 24h;
DOI:10.1021/jo0505270

Reference yield:

: 777891-09-5
tert-butyl-(7-iodo-heptyloxy)-diphenyl-silane

: 861997-79-7
5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole

Guidance literature:: Multi-step reaction with 6 steps

1: t-BuLi / tetrahydrofuran; pentane / 1 h / -78 °C

2: 0.94 g / TBAF / tetrahydrofuran / 1 h / 20 °C

3: 98 percent / PPh₃; diisopropyl azodicarboxylate / 0.17 h

4: 85 percent / CuCl₂; CuO / acetone; H₂O / 0.75 h / 20 °C

5: 85 percent / (NH₄)6Mo₇O₂₄*H₂O; aq. H₂O₂ / ethanol / 24 h / 20 °C

6: 92 percent / TMSOTf / CH₂Cl₂ / 24 h / -5 °C

With ammonium heptamolybdate; trimethylsilyl trifluoromethanesulfonate; di-isopropyl azodicarboxylate; tetrabutyl ammonium fluoride; dihydrogen peroxide; tert.-butyl lithium; triphenylphosphine; copper(II) oxide; copper dichloride; In tetrahydrofuran; ethanol; dichloromethane; water; acetone; pentane;
DOI:10.1021/jo0505270

Reference yield:

: 861997-73-1
7-(2-nonyl-[1,3]dithian-2-yl)-heptan-1-ol

: 861997-79-7
5-[7-(2-nonyl-[1,3]dioxolan-2-yl)-heptane-1-sulfonyl]-1-phenyl-1H-tetrazole

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / PPh₃; diisopropyl azodicarboxylate / 0.17 h

2: 85 percent / CuCl₂; CuO / acetone; H₂O / 0.75 h / 20 °C

3: 85 percent / (NH₄)6Mo₇O₂₄*H₂O; aq. H₂O₂ / ethanol / 24 h / 20 °C

4: 92 percent / TMSOTf / CH₂Cl₂ / 24 h / -5 °C

With ammonium heptamolybdate; trimethylsilyl trifluoromethanesulfonate; di-isopropyl azodicarboxylate; dihydrogen peroxide; triphenylphosphine; copper(II) oxide; copper dichloride; In ethanol; dichloromethane; water; acetone;
DOI:10.1021/jo0505270