DT-TM acid

Base Information

• Chemical Name: DT-TM acid
• CAS No.: 115695-23-3
• Molecular Formula: C₁₉H₃₀O₆Si₂
• Molecular Weight: 410.615
• Mol file: 115695-23-3.mol

Synonyms:DT-TM acid

Chemical Property of DT-TM acid

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of DT-TM acid

There total 2 articles about DT-TM acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

tris(2-(trimethylsilyl)ethyl) benzene-1,3,5-tricarboxylate → DT-TM acid (115695-23-3)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 23 ℃; for 16h;

DOI:10.1002/anie.202002638

Reference yield:

2-(Trimethylsilyl)ethanol (2916-68-9) + benzene-1,3,5-tricarboxylic acid (554-95-0) → Benzene-1,3,5-tricarboxylic acid 1-(2-trimethylsilanyl-ethyl) ester + DT-TM acid (115695-23-3) + tris(2-(trimethylsilyl)ethyl) benzene-1,3,5-tricarboxylate

Guidance literature:

With sodium hydroxide; 1,1'-carbonyldiimidazole; Product distribution; multistep reaction; 1.) DMF, 1 h, 2.) DMF, overnight; var. solvents and reagent ratio; examination of imidazolide formation;;

Reference yield: 98.0%

DT-TM acid (115695-23-3) → bis(2-(trimethylsilyl)ethyl) 5-carbamoylisophthalate

Guidance literature:

DT-TM acid; With oxalyl dichloride; N,N-dimethyl-formamide; In dichloromethane; at 23 ℃; for 12.166h; Inert atmosphere;

With ammonium hydroxide; In tetrahydrofuran; at 23 ℃; for 2.166h; Inert atmosphere;

DOI:10.1002/anie.202002638

upstream raw materials:

2-(Trimethylsilyl)ethanol

benzene-1,3,5-tricarboxylic acid

Refernces

• 1、 Matsunaga, Satoshi,Hasada, Ken-Ichi,Sugiura, Kenji,Kitamura, Naoki,Kudo, Yuri,Endo, Nanako,Mori, Wasuke. "Hetero bi-paddle-wheel coordination networks: A new synthetic route to Rh-containing metal - Organic frameworks". . p. 433 - 438. Retrieved 2012.