tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

Base Information

Chemical Name:tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)
CAS No.:1363597-60-7
Molecular Formula:C₄₀H₄₈N₆O₉
Molecular Weight:756.856
Hs Code.:

Synonyms:tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

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Chemical Property of tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

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Technology Process of tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

There total 3 articles about tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 1363597-59-4
tetraethyl (4′-bromomethyl-2,2′:6′,2′-terpyridine-6,6′-diyl)bis(methylenenitrilo)tetrakis(acetate)

: 123-30-8
4-amino-phenol

: 1363597-60-7
tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

Guidance literature:: 4-amino-phenol; With sodium hydride; In acetonitrile; at 20 ℃; for 0.25h; Inert atmosphere;

tetraethyl (4′-bromomethyl-2,2′:6′,2′-terpyridine-6,6′-diyl)bis(methylenenitrilo)tetrakis(acetate); In acetonitrile; Inert atmosphere;
DOI:10.1021/ic202195a

Reference yield:

: 372520-85-9
ethyl 6,6''-bis-(bromomethyl)-2,2':6',2''-terpyridine-4'-carboxylate

: 1363597-60-7
tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

Guidance literature:: Multi-step reaction with 4 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 2.5 h / 0 °C

2.1: sodium hydride / acetonitrile / 1 h / Inert atmosphere

2.2: Inert atmosphere

3.1: phosphorus tribromide / tetrahydrofuran / 2 h / 20 °C

4.1: sodium hydride / acetonitrile / 0.25 h / 20 °C / Inert atmosphere

4.2: Inert atmosphere

With lithium aluminium tetrahydride; phosphorus tribromide; sodium hydride; In tetrahydrofuran; acetonitrile;
DOI:10.1021/ic202195a

Reference yield:

: 1363597-57-2
4'-hydroxymethyl-6-6''-bis(bromomethyl)-2,2':6',2''-terpyridine

: 1363597-60-7
tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / acetonitrile / 1 h / Inert atmosphere

1.2: Inert atmosphere

2.1: phosphorus tribromide / tetrahydrofuran / 2 h / 20 °C

3.1: sodium hydride / acetonitrile / 0.25 h / 20 °C / Inert atmosphere

3.2: Inert atmosphere

With phosphorus tribromide; sodium hydride; In tetrahydrofuran; acetonitrile;
DOI:10.1021/ic202195a