4-tert.-Butylphenyl-phosphorige Saeure-dichlorid

Base Information

• Chemical Name: 4-tert.-Butylphenyl-phosphorige Saeure-dichlorid
• CAS No.: 13172-88-8
• Molecular Formula: C₁₀H₁₃Cl₂OP
• Molecular Weight: 251.092
• Mol file: 13172-88-8.mol

Synonyms:4-tert.-Butylphenyl-phosphorige Saeure-dichlorid

Chemical Property of 4-tert.-Butylphenyl-phosphorige Saeure-dichlorid

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-tert.-Butylphenyl-phosphorige Saeure-dichlorid

There total 2 articles about 4-tert.-Butylphenyl-phosphorige Saeure-dichlorid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4-(tert-butyl)phenyl)dichlorophosphine (60692-79-7) → 4-tert.-Butylphenyl-phosphorige Saeure-dichlorid (13172-88-8)

Guidance literature:

With sulfuryl dichloride; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/jacs.8b13435

Reference yield:

4-tert.-Butylphenyl-(bis-diethylamino)-phosphin (60692-86-6) → 4-tert.-Butylphenyl-phosphorige Saeure-dichlorid (13172-88-8)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogenchloride / diethyl ether / 3.5 h / 0 - 20 °C / Inert atmosphere

2: sulfuryl dichloride / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

With hydrogenchloride; sulfuryl dichloride; In diethyl ether; dichloromethane;

DOI:10.1021/jacs.8b13435

Reference yield: 56.0%

4-tert.-Butylphenyl-phosphorige Saeure-dichlorid (13172-88-8) + 4-tert-butylphenyl phosphonic acid (100134-03-0) → C30H39O6P3

Guidance literature:

In toluene; for 4h; Reflux;

DOI:10.1021/jacs.8b13435

upstream raw materials:

4-tert.-Butylphenyl-(bis-diethylamino)-phosphin

(4-(tert-butyl)phenyl)dichlorophosphine

Downstream raw materials:

4-tert-butylphenyl phosphonic acid