14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester

Base Information

• Chemical Name: 14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester
• CAS No.: 1111320-86-5
• Molecular Formula: C₂₉H₃₉NO₁₀
• Molecular Weight: 561.629
• Mol file: 1111320-86-5.mol

Synonyms:14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester

Chemical Property of 14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester

There total 1 articles about 14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

benzylamine (100-46-9) + 4,5-bis{2-[2-(2-(toluol-4-sulfonyloxy)ethoxy)ethoxy]ethoxy}phthalic acid dimethyl ester (841260-38-6) → 14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester (1111320-86-5)

Guidance literature:

With potassium carbonate; potassium iodide; In water; acetonitrile; at 80 ℃;

DOI:10.1016/j.tet.2008.10.086

Reference yield:

14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid dimethyl ester (1111320-86-5) → 14-benzyl-6,7,9,10,13,14,15,16,18,19,21,22-dodecahydro-12H-5,8,11,17,20,23-hexaoxa-14-aza-benzocycloheneicosene-2,3-dicarboxylic acid disodium salt

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; methanol; water; at 40 ℃; for 48h;

DOI:10.1016/j.tet.2008.10.086

upstream raw materials:

benzylamine

4,5-bis{2-[2-(2-(toluol-4-sulfonyloxy)ethoxy)ethoxy]ethoxy}phthalic acid dimethyl ester