1,1-Bis(trimethylsilyl)-2-(trimethylsiloxy)-2-(1-adamantyl)-1-silaethene

Base Information

• Chemical Name: 1,1-Bis(trimethylsilyl)-2-(trimethylsiloxy)-2-(1-adamantyl)-1-silaethene
• CAS No.: 72189-54-9
• Molecular Formula: C20H42 O Si4
• Molecular Weight: 410.895
• DSSTox Substance ID: DTXSID90222517
• Nikkaji Number: J211.375I
• Mol file: 72189-54-9.mol

Synonyms:72189-54-9;1,1-Bis(trimethylsilyl)-2-(trimethylsiloxy)-2-(1-adamantyl)-1-silaethene;DTXSID90222517;2-(1-adamantyl)-1,1-bis(trimethyl-silyl)-2-trimethylsiloxy-1-silaethene

Chemical Property of 1,1-Bis(trimethylsilyl)-2-(trimethylsiloxy)-2-(1-adamantyl)-1-silaethene

Chemical Property:

• PSA: 9.23000
• LogP: 6.09390
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 410.23127210
• Heavy Atom Count: 25
• Complexity: 502

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)OC(=[Si]([Si](C)(C)C)[Si](C)(C)C)C12CC3CC(C1)CC(C3)C2

Technology Process of 1,1-Bis(trimethylsilyl)-2-(trimethylsiloxy)-2-(1-adamantyl)-1-silaethene

There total 3 articles about 1,1-Bis(trimethylsilyl)-2-(trimethylsiloxy)-2-(1-adamantyl)-1-silaethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1-adamantanecarbonyltris(trimethylsilyl)silane (72189-53-8) → 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsilyl)-1-silene (72189-54-9)

Guidance literature:

In diethyl ether; at 6 ℃; for 12h; Irradiation;

DOI:10.1021/ja00385a019

Reference yield:

1-Adamantanecarbonyl chloride (2094-72-6) → 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsilyl)-1-silene (72189-54-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 64 percent / cyclopentane / 1 h / -60 deg C -> 20 deg C

2: 70 percent / diethyl ether / 12 h / 6 °C / Irradiation

In diethyl ether; Cyclopentane;

DOI:10.1021/ja00385a019

Reference yield:

tris(trimethylsilyl)silyllithium (4110-02-5) → 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsilyl)-1-silene (72189-54-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 64 percent / cyclopentane / 1 h / -60 deg C -> 20 deg C

2: 70 percent / diethyl ether / 12 h / 6 °C / Irradiation

In diethyl ether; Cyclopentane;

DOI:10.1021/ja00385a019

upstream raw materials:

1-adamantanecarbonyltris(trimethylsilyl)silane

1-Adamantanecarbonyl chloride

tris(trimethylsilyl)silyllithium

Downstream raw materials:

C₅₃H₉₈O₃Si₈

C₃₁H₅₂OSi₄

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