C₃₅H₄₉NO₈

Base Information

• Chemical Name: C₃₅H₄₉NO₈
• CAS No.: 1268471-44-8
• Molecular Formula: C₃₅H₄₉NO₈
• Molecular Weight: 611.776
• Mol file: 1268471-44-8.mol

Synonyms:C₃₅H₄₉NO₈

Chemical Property of C₃₅H₄₉NO₈

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₅H₄₉NO₈

There total 8 articles about C₃₅H₄₉NO₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

(S,Z)-5-(((2R,3R,5S,6S)-2,5-dimethyl-6-((E)-3-methylpenta-2,4-dien-1-yl)tetrahydro-2H-pyran-3-yl)amino)-5-oxopent-3-en-2-yl acetate (882028-31-1) + C17H22O4 (1268471-01-7) → C35H49NO8 (1268471-44-8)

Guidance literature:

With [RuCl₂(1,3-dimesitylimidazolin-2-ylidene)(=CH-2-{2-PrO}-5-NO₂C₆H₃)]; p-benzoquinone; In 1,2-dichloro-ethane; at 23 - 40 ℃; open atmosphere;

DOI:10.1002/chem.201002402

Reference yield:

C18H26O5 (1268470-99-0) → C35H49NO8 (1268471-44-8)

Guidance literature:

Multi-step reaction with 4 steps

1: sodium periodate / tetrahydrofuran; water / 1.75 h / 23 °C / open atmosphere

2: L-Selectride / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

3: sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0 - 23 °C / Saturated solution; under air

4: [RuCl₂(1,3-dimesitylimidazolin-2-ylidene)(=CH-2-{2-PrO}-5-NO₂C₆H₃)]; p-benzoquinone / 1,2-dichloro-ethane / 23 - 40 °C / open atmosphere

With sodium periodate; [RuCl₂(1,3-dimesitylimidazolin-2-ylidene)(=CH-2-{2-PrO}-5-NO₂C₆H₃)]; L-Selectride; sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; p-benzoquinone; In tetrahydrofuran; dichloromethane; water; 1,2-dichloro-ethane;

DOI:10.1002/chem.201002402

Reference yield:

C17H24O4 (1268471-00-6) → C35H49NO8 (1268471-44-8)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0 - 23 °C / Saturated solution; under air

2: [RuCl₂(1,3-dimesitylimidazolin-2-ylidene)(=CH-2-{2-PrO}-5-NO₂C₆H₃)]; p-benzoquinone / 1,2-dichloro-ethane / 23 - 40 °C / open atmosphere

With [RuCl₂(1,3-dimesitylimidazolin-2-ylidene)(=CH-2-{2-PrO}-5-NO₂C₆H₃)]; sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; p-benzoquinone; In dichloromethane; water; 1,2-dichloro-ethane;

DOI:10.1002/chem.201002402

upstream raw materials:

(S,Z)-5-(((2R,3R,5S,6S)-2,5-dimethyl-6-((E)-3-methylpenta-2,4-dien-1-yl)tetrahydro-2H-pyran-3-yl)amino)-5-oxopent-3-en-2-yl acetate

C₁₇H₂₂O₄

(3R,4R,5R)-7,7-dimethyl-5-vinyl-1,6-dioxaspiro[2.5]octan-4-ol

C₁₈H₂₄O₄