trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

Base Information

Chemical Name:trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)
CAS No.:464896-32-0
Molecular Formula:C₉₀H₈₄F₁₀P₄Pt₂
Molecular Weight:1869.7
Hs Code.:

trans,trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P-(CH<sub>2</sub>)11PPh<sub>2</sub>Pt-(C<sub>2</sub>)4Pt-(Ph<sub>2</sub>P(CH<sub>2</sub>)11P-Ph<sub>2</sub>)(C<sub>6</sub>F<sub>5</sub>)

Synonyms:trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

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Chemical Property of trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

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Technology Process of trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

There total 2 articles about trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 464896-38-6,464896-36-4
trans,trans-(C₆F₅)(Ph₂P-(CH₂)14PPh₂)Pt-(C₂)4Pt-(Ph₂P(CH₂)14Ph₂P-)(C₆F₅)

: 82195-41-3
(C₆H₅)2P(CH₂)11P(C₆H₅)2

: 464896-32-0
trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

Guidance literature:: In dichloromethane; a Schlenk flack was charged with Pt-complex and CH2Cl2, a soln. of diphosphine in CH2Cl2 was passed through a silica gel pad with stirring, 2 h of stirring; the solvent was removed by oil pump vac., ethanol was added, filtered, washed with ethanol, dried by oil pump vac.;
DOI:10.1021/ja0716103

Reference yield: 80.0%

: trans,trans-(C₆F₅)((p-tolyl)3P)2Pt(CC)4Pt(P(p-tolyl)3)2(C₆F₅)

: 82195-41-3
(C₆H₅)2P(CH₂)11P(C₆H₅)2

: 464896-32-0
trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

Guidance literature:: In dichloromethane; treated with phosphane in moderate dilute conditions;
DOI:10.1002/1521-3773(20020603)41:11<1871::AID-ANIE1871>3.0.CO;2-V