methyl phenyl sulfoxide-α-13C

Base Information

• Chemical Name: methyl phenyl sulfoxide-α-13C
• CAS No.: 207990-68-9
• Molecular Formula: C₇H₈OS
• Molecular Weight: 141.195
• Mol file: 207990-68-9.mol

Synonyms:methyl phenyl sulfoxide-α-13C

Chemical Property of methyl phenyl sulfoxide-α-13C

Chemical Property:

Purity/Quality:

99% atom 13C ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl phenyl sulfoxide-α-13C

There total 3 articles about methyl phenyl sulfoxide-α-13C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[13C]methyl phenyl sulfide (91597-65-8) → methyl phenyl sulfoxide-α-13C (207990-68-9)

Guidance literature:

With dihydrogen peroxide; In ethanol; Cooling;

DOI:10.1002/jlcr.3185

Reference yield:

thiophenol (108-98-5) → methyl phenyl sulfoxide-α-13C (207990-68-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium methoxide / methanol / -10 °C

1.2: 74 percent / methanol / 1 h / 20 °C

2.1: 95 percent / aq. metaperiodate / 3 h

With periodate; sodium methylate; In methanol;

DOI:10.1021/ja051589a

Reference yield:

thiophenol (108-98-5) → methyl phenyl sulfoxide-α-13C (207990-68-9)

Guidance literature:

Multi-step reaction with 2 steps

1: DBU

2: NaIO₄

With sodium periodate; 1,8-diazabicyclo[5.4.0]undec-7-ene;

DOI:10.1021/ja9740273

upstream raw materials:

[¹³C]methyl phenyl sulfide

thiophenol

Downstream raw materials:

trans-4-(phenylsulfinyl)[4-13C]crotonic acid methyl ester

4,4-diethoxy-1-(phenylsulfinyl)[1-13C]butan-2-one

4-phenylsulfinyl-2[1,3,4-13C₃]butenoic acid

methyl 4-(phenylsulfinyl)2-[3,4-13C₂]butenoate