methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

Base Information

Chemical Name:methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate
CAS No.:1250395-73-3
Molecular Formula:C₇₄H₁₂₀O₁₅Si₃
Molecular Weight:1334.01
Hs Code.:

methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

Synonyms:methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

Suppliers and Price of methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

There total 1 articles about methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1250395-72-2
methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11,13-dihydroxy-3,7-dimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

: 420-37-1
trimethoxonium tetrafluoroborate

: 1250395-73-3
methyl (2S,3R,5S,7R,8R,9S,11S,13S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7,13-trimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-16-icosenoate

Guidance literature:: With 2,6-di-tert-butyl-pyridine; In dichloromethane; at 0 - 20 ℃; for 5h; regioselective reaction;
DOI:10.1002/anie.201002293