3-methyl-2-azide methylbenzoate

Base Information

• Chemical Name: 3-methyl-2-azide methylbenzoate
• CAS No.: 1618636-92-2
• Molecular Formula: C₉H₉N₃O₂
• Molecular Weight: 191.189
• Mol file: 1618636-92-2.mol

Synonyms:3-methyl-2-azide methylbenzoate

Chemical Property of 3-methyl-2-azide methylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of 3-methyl-2-azide methylbenzoate

There total 2 articles about 3-methyl-2-azide methylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

methyl 2-amino-3-methylbenzoate (22223-49-0) → 3-methyl-2-azide methylbenzoate (1618636-92-2)

Guidance literature:

methyl 2-amino-3-methylbenzoate; With hydrogenchloride; sodium nitrite; In water; for 0.5h;

With sodium azide; Reflux;

DOI:10.1039/c4ob00923a

Reference yield:

methyl 3-methyl-2-nitrobenzoate (5471-82-9) → 3-methyl-2-azide methylbenzoate (1618636-92-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: zinc; acetic acid / dichloromethane / 5 h / Reflux

2.1: hydrogenchloride; sodium nitrite / water / 0.5 h

2.2: Reflux

With hydrogenchloride; acetic acid; zinc; sodium nitrite; In dichloromethane; water;

DOI:10.1039/c4ob00923a

upstream raw materials:

methyl 2-amino-3-methylbenzoate

methyl 3-methyl-2-nitrobenzoate