p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside

Base Information

• Chemical Name: p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside
• CAS No.: 903588-03-4
• Molecular Formula: C₃₆H₃₃Cl₃O₁₀S₂
• Molecular Weight: 796.143
• Mol file: 903588-03-4.mol

Synonyms:p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside

Chemical Property of p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside

There total 1 articles about p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1-methyl-3-(2,2,2-trichloroethoxysulfuryl)-3H-imidazol-1-ium triflate + p-tolyl 2,3-di-O-benzoyl-6-O-benzyl-1-thio-β-D-glucopyranoside → p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside (903588-03-4)

Guidance literature:

With 1-methyl-1H-imidazole; In tetrahydrofuran; at 0 - 20 ℃; for 108h;

DOI:10.1002/anie.200600153

Reference yield: 96.0%

p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside (903588-03-4) → C34H32O10S2*H3N

Guidance literature:

With ammonium formate; zinc; In methanol; at 20 ℃; for 4h;

DOI:10.1002/anie.200600153

Reference yield: 74.0%

p-tolyl 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-1-thio-β-D-glucopyranoside (903588-03-4) → 2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-D-glucopyranose

Guidance literature:

With N-Bromosuccinimide; water; In acetone; at 0 ℃; for 0.333333h;

DOI:10.1002/anie.200600153

Downstream raw materials:

2,3-di-O-benzoyl-4-O-trichloroethylsulfo-6-O-benzyl-α-D-glucopyranotrichloroacetimidate