(S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether

Base Information

Chemical Name:(S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether
CAS No.:99837-77-1
Molecular Formula:C₁₄H₂₂O₃S₂
Molecular Weight:302.459
Hs Code.:

Synonyms:(S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether

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Chemical Property of (S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether

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Technology Process of (S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether

There total 2 articles about (S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.6%

: 88526-08-3
(S)-(+)-6-(phenylsulfonyl)-2-hexanol

: 67-68-5,8070-53-9
dimethyl sulfoxide

: 67886-01-5
6-(phenylsulfonyl)-2-hexanone

: 99837-77-1
(S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether

: Acetic acid (S)-5-benzenesulfonyl-1-methyl-pentyloxymethyl ester

Guidance literature:: With acetic anhydride; acetic acid; for 44h;
DOI:10.1021/ja00262a015

Reference yield:

: 67886-01-5
6-(phenylsulfonyl)-2-hexanone

: 99837-77-1
(S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 73 percent / yeast culture C_. guillermonde

2: 72 percent / acetic acid, acetic anhydride / 44 h

With acetic anhydride; acetic acid;
DOI:10.1021/ja00262a015

Reference yield:

: 99837-77-1
(S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether

: 4(R),1'(R),2'(S),4'(S),6'(S)-methyl 4-acetoxy-4-(2-(6-hydroxy-1-(E)-heptenyl)-4-<(methoxyethoxy)methoxy>cyclopentyl)-2-(phenylsulfinyl)butanoate

Guidance literature:: Multi-step reaction with 11 steps

1: 1.) n-butyllithium / 1.) THF, hexane, -78 deg C, 20 min, 2.) THF, hexane, -78 deg C, 40 min

2: 97 percent / sodium borohyride / ethanol / 0.67 h / Ambient temperature

3: 97 percent / (dimethylamino)pyridine / pyridine / 3 h / Ambient temperature

4: 64.2 percent / 6percent sodium amalgam / ethyl acetate; methanol / 6.5 h / -20 °C

5: 64 percent / 1N aq. HCl / tetrahydrofuran / 2.25 h / Ambient temperature

6: 89 percent / pyridine / 10 h / Ambient temperature

7: 93 percent / sodium methoxide / methanol; diethyl ether / 0.25 h / 0 °C

8: 1.) lithium diisopropylamide / 1.) THF, 0 deg C, 0.5 h, 2.) THF, room temperature, 18 h

9: diethyl ether

10: DMAP / pyridine; CH₂Cl₂ / 3 h / 0 °C

11: 75 percent / NCS, silver nitrate / acetonitrile; H₂O / 1.3 h / Ambient temperature

With hydrogenchloride; dmap; sodium tetrahydroborate; sodium amalgam; N-chloro-succinimide; n-butyllithium; sodium methylate; silver nitrate; lithium diisopropyl amide; In tetrahydrofuran; pyridine; methanol; diethyl ether; ethanol; dichloromethane; water; ethyl acetate; acetonitrile;
DOI:10.1021/ja00262a015