methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

Base Information

Chemical Name:methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose
CAS No.:123077-03-2
Molecular Formula:C₁₄H₁₆O₅
Molecular Weight:264.278
Hs Code.:

Synonyms:methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

Suppliers and Price of methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

There total 7 articles about methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 104652-05-3
methyl 3-O-benzoyl-2,6-dideoxy-α-D-ribo-hexopyranoside

: 123077-03-2
methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

Guidance literature:: With mol. siev. 3-A; sodium acetate; pyridinium chlorochromate; In dichloromethane; for 2h; Ambient temperature;
DOI:10.1021/jo00278a035

Reference yield:

: 93960-50-0
Benzoic acid (2S,3S,4S,6S)-2-bromomethyl-3-hydroxy-6-methoxy-tetrahydro-pyran-4-yl ester

: 123077-03-2
methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

Guidance literature:: Multi-step reaction with 2 steps

1: Bu₃SnH; AIBN / benzene

2: 69 percent / pyridinium chlorochromate / CH₂Cl₂

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; pyridinium chlorochromate; In dichloromethane; benzene;
DOI:10.1002/1521-3773(20010202)40:3<607::AID-ANIE607>3.0.CO;2-8

Reference yield:

: 16718-95-9
methyl 4,6-O-benzylidene-2-deoxy-α-D-altropyranoside

: 123077-03-2
methyl 3-O-benzoyl-2,6-dideoxy-α-D-erythro-hexopyranosid-4-ulose

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / N-bromosuccinimide, barium carbonate / CCl₄ / 0.33 h / 45 °C

2: tributyltin hydride, azobisisobutyronitrile (AIBN) / toluene / 2 h / 60 °C

3: 92 percent / pyridinium chlorochromate, sodium acetate, mol. siev. 3-A / CH₂Cl₂ / 2 h / Ambient temperature

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); mol. siev. 3-A; tri-n-butyl-tin hydride; sodium acetate; barium carbonate; pyridinium chlorochromate; In tetrachloromethane; dichloromethane; toluene;
DOI:10.1021/jo00278a035