(1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

Base Information

Chemical Name:(1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate
CAS No.:1318778-98-1
Molecular Formula:C₁₈H₂₆O₂
Molecular Weight:274.403
Hs Code.:

Synonyms:(1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

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Chemical Property of (1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

Chemical Property:

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Technology Process of (1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

There total 2 articles about (1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 1318778-97-0
2,4-dimethyl-pent-3-yl α-diazopropionate

: 1318778-98-1
(1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

: (1S,2R)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

Guidance literature:: With dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate] dihydrate; In dichloromethane; at -60 ℃; for 7h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1016/j.tetlet.2011.06.008

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 1318778-97-0
2,4-dimethyl-pent-3-yl α-diazopropionate

: 1318778-98-1
(1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

: (1S,2R)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

: 2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

Guidance literature:: With dirhodium(II) tetrakis[N-tetrafluorophthaloyl-(S)-tert-leucinate]; In dichloromethane; at -60 ℃; for 3h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1016/j.tetlet.2011.06.008

Reference yield: 98.0%

: 1318778-98-1
(1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate

: (1R,2S)-E-1-hydroxymethyl-1-methyl-2-phenylcyclopropane

Guidance literature:: (1R,2S)-2,4-dimethyl-3-pentyl 1-methyl-2-phenylcyclopropane-1-carboxylate; With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 20 ℃; for 3h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; water; at 0 ℃;
DOI:10.1016/j.tetlet.2011.06.008