dichloro(2,4,6-tri-isopropylphenyl)arsine

Base Information

• Chemical Name: dichloro(2,4,6-tri-isopropylphenyl)arsine
• CAS No.: 133745-10-5
• Molecular Formula: C₁₅H₂₃AsCl₂
• Molecular Weight: 349.175
• Mol file: 133745-10-5.mol

Synonyms:dichloro(2,4,6-tri-isopropylphenyl)arsine

Chemical Property of dichloro(2,4,6-tri-isopropylphenyl)arsine

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of dichloro(2,4,6-tri-isopropylphenyl)arsine

There total 1 articles about dichloro(2,4,6-tri-isopropylphenyl)arsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

2,4,6-triisopropyl-1-bromobenzene (21524-34-5) → dichloro(2,4,6-tri-isopropylphenyl)arsine (133745-10-5)

Guidance literature:

2,4,6-triisopropyl-1-bromobenzene; With magnesium; In tetrahydrofuran; at 90 ℃; for 3h;

With arsenic trichloride; In tetrahydrofuran; at -78 ℃;

With zinc(II) chloride; In tetrahydrofuran; at 20 ℃; for 72h; Reagent/catalyst; Solvent; Temperature;

DOI:10.1039/d0cc07533g

Reference yield: 85.0%

dichloro(2,4,6-tri-isopropylphenyl)arsine (133745-10-5) → C15H25As

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 20 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c6dt00776g

Reference yield: 65.0%

dichloro(2,4,6-tri-isopropylphenyl)arsine (133745-10-5) → C45H69As3

Guidance literature:

With zinc; trimethylphosphane; In tetrahydrofuran; at 20 ℃; for 16h;

DOI:10.1039/d0cc07533g

upstream raw materials:

2,4,6-triisopropyl-1-bromobenzene