2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone

Base Information

• Chemical Name: 2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone
• CAS No.: 66118-69-2
• Molecular Formula: C₃₀H₂₂FeO₃
• Molecular Weight: 486.35
• Mol file: 66118-69-2.mol

Synonyms:2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone

Chemical Property of 2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone

There total 1 articles about 2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

cyclopentadienyl(3-phenyl-2-propynyl)dicarbonyliron + diphenyl ketene (525-06-4) → 2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone (66118-69-2)

Guidance literature:

In dichloromethane; benzene; N2-atmosphere; addn. of slight excess of ketene (in C6H6) to Fe-complex soln. (in CH2Cl2) at -40°C, warming to room temp., stirring (5 h); concn. (reduced pressure), chromy. (Al2O3, pentane/CH2Cl2=1:3), evapn., crystn. (CH2Cl2/pentane); elem. anal.;

DOI:10.1016/S0020-1693(00)95707-4

Reference yield: 43.0%

2-phenyl-3-(cyclopentadienyl dicarbonyl iron)-5,5-diphenyl-2-cyclopentenone (66118-69-2) + methyllithium (917-54-4) → 2-(cyclopentadienyl iron dicarbonyl)-4-methyl-3,5,5-triphenylcyclopentadiene (139728-56-6)

Guidance literature:

In tetrahydrofuran; diethyl ether; byproducts: 3-methyl-2,5,5-triphenyl-2-cyclopentenone; N2-atmosphere; dropwise addn. of MeLi (in Et2O) to Fe-complex (in THF) at 0°C, stirring at 0°C for 3 min or 3 h; treatment with satd. NaCl, extn. into ether, drying (Na2SO4), chromy. (SiO2, petroleum ether/Me2CO=10:1); yield increasing from 43% (3 min reaction time) to 47% (3 h);

DOI:10.1016/0022-328X(94)05071-I

upstream raw materials:

diphenyl ketene

Downstream raw materials:

2-(cyclopentadienyl iron dicarbonyl)-4-methyl-3,5,5-triphenylcyclopentadiene