anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.1^2,5.0^1,6>dodec-7-ene

Base Information

• Chemical Name: anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.1^2,5.0^1,6>dodec-7-ene
• CAS No.: 75347-83-0
• Molecular Formula: C₂₄H₂₄N₂O₂
• Molecular Weight: 372.467

Synonyms:anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.1^2,5.0^1,6>dodec-7-ene

Chemical Property of anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.1^2,5.0^1,6>dodec-7-ene

Chemical Property:

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Technology Process of anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.1^2,5.0^1,6>dodec-7-ene

There total 3 articles about anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.1^2,5.0^1,6>dodec-7-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-dimethylidenebicyclo<2.2.1>heptan-7-one (38680-06-7) → anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.12,5.01,6>dodec-7-ene (75347-83-0)

Guidance literature:

Multi-step reaction with 3 steps

1: lithium-tri-tert.-butoxyaluminum hydride / tetrahydrofuran

2: 83 percent / benzene / 36 h / Heating

3: 1.) irradiation, pentane, -10 deg C, 72h, 2.) hexane, reflux, 48h

With lithium tri-t-butoxyaluminum hydride; In tetrahydrofuran; benzene;

DOI:10.1021/jo01314a050

Reference yield:

2,3-dimethylene-anti-7-norbornanol (38680-07-8,38680-08-9) → anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.12,5.01,6>dodec-7-ene (75347-83-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 83 percent / benzene / 36 h / Heating

2: 1.) irradiation, pentane, -10 deg C, 72h, 2.) hexane, reflux, 48h

In benzene;

DOI:10.1021/jo01314a050

Reference yield:

2,3-dimethylene-anti-7-norbornyl acetate (75347-89-6) + diazodiphenylmethane (908093-98-1) → anti-12-acetoxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.12,5.01,6>dodec-7-ene (75347-83-0)

Guidance literature:

Yield given. Multistep reaction; 1.) irradiation, pentane, -10 deg C, 72h, 2.) hexane, reflux, 48h;

DOI:10.1021/jo01314a050

upstream raw materials:

2,3-dimethylene-anti-7-norbornyl acetate

diazodiphenylmethane

2,3-dimethylidenebicyclo<2.2.1>heptan-7-one

2,3-dimethylene-anti-7-norbornanol

Downstream raw materials:

anti-12-hydroxy-exo-9,9-diphenyl-7,8-diazatetracyclo<4.3.2.1^2,5.0^1,6>dodec-7-ene

Acetic acid (6R,8R)-5-benzhydrylidene-tricyclo[4.2.1.0^2,8]non-7-yl ester

C₂₄H₂₄O₂

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