Technology Process of C48H64O8Si
There total 5 articles about C48H64O8Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium tetrahydroborate; ethanol;
at -15 ℃;
for 15h;
optical yield given as %de;
Inert atmosphere;
DOI:10.1021/ja203034k
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: sodium hexamethyldisilazane / tetrahydrofuran; N,N-dimethyl-formamide / 0.03 h / Inert atmosphere; Cooling with ice
1.2: 0.33 h / 0 °C / Inert atmosphere
2.1: n-butyllithium; diisopropylamine / tetrahydrofuran; pentane / 0.23 h / -78 - 0 °C / Inert atmosphere
2.2: 0.77 h / -78 °C / Inert atmosphere
2.3: -78 °C
3.1: pyridinium p-toluenesulfonate / 3 h / 45 °C / Inert atmosphere
4.1: sodium tetrahydroborate; ethanol / 15 h / -15 °C / Inert atmosphere
With
sodium tetrahydroborate; n-butyllithium; ethanol; sodium hexamethyldisilazane; pyridinium p-toluenesulfonate; diisopropylamine;
In
tetrahydrofuran; N,N-dimethyl-formamide; pentane;
DOI:10.1021/ja203034k
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: n-butyllithium; diisopropylamine / tetrahydrofuran; pentane / 0.23 h / -78 - 0 °C / Inert atmosphere
1.2: 0.77 h / -78 °C / Inert atmosphere
1.3: -78 °C
2.1: pyridinium p-toluenesulfonate / 3 h / 45 °C / Inert atmosphere
3.1: sodium tetrahydroborate; ethanol / 15 h / -15 °C / Inert atmosphere
With
sodium tetrahydroborate; n-butyllithium; ethanol; pyridinium p-toluenesulfonate; diisopropylamine;
In
tetrahydrofuran; pentane;
DOI:10.1021/ja203034k
