(2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride

Base Information

• Chemical Name: (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride
• CAS No.: 565177-87-9
• Molecular Formula: C₂₅H₂₈Cl₂CoN₂
• Molecular Weight: 486.41
• Mol file: 565177-87-9.mol

Synonyms:(2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride

Chemical Property of (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride

There total 5 articles about (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.5%

(2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine (202405-48-9) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride (565177-87-9)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 6h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2015.05.004

Reference yield:

phenylboronic acid (98-80-6) → (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride (565177-87-9)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / toluene / 80 °C / Inert atmosphere

2: formic acid / ethanol / 24 h / Inert atmosphere; Reflux

3: tetrahydrofuran / 6 h / 20 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; formic acid; potassium carbonate; In tetrahydrofuran; ethanol; toluene;

DOI:10.1016/j.jorganchem.2015.05.004

Reference yield:

1-(6-bromopyridin-2-yl)-ethanone (49669-13-8) → (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride (565177-87-9)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / toluene / 80 °C / Inert atmosphere

2: formic acid / ethanol / 24 h / Inert atmosphere; Reflux

3: tetrahydrofuran / 6 h / 20 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; formic acid; potassium carbonate; In tetrahydrofuran; ethanol; toluene;

DOI:10.1016/j.jorganchem.2015.05.004

upstream raw materials:

(2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine

methyl(2-phenylpyridin-6-yl)-methanone

2,6-diisopropylbenzenamine

cobalt(II) chloride