(3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane

Base Information

Chemical Name:(3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane
CAS No.:866007-04-7
Molecular Formula:C₂₂H₃₅NO₄Si
Molecular Weight:405.61
Hs Code.:

Synonyms:(3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane

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Chemical Property of (3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane

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Technology Process of (3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane

There total 4 articles about (3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: (S)-N-(benzyloxycarbonyl)[(3-methylbut-2-enyl)di(isopropyl)silanyloxy]isoserinal

: 866007-04-7
(3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane

Guidance literature:: In ⁽²⁾H₈-toluene; at 120 ℃; for 30h;
DOI:10.1021/jo050644v

Reference yield:

: 866007-58-1
(S)-methyl N-(benzyloxycarbonyl)[(3-methylbut-2-enyl)di(isopropyl)silanyloxy]isoserinate

: 866007-04-7
(3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / DIBAL / CH₂Cl₂ / 1 h / -78 °C

2: 91 percent / toluene-d8 / 30 h / 120 °C

With diisobutylaluminium hydride; In dichloromethane; ⁽²⁾H₈-toluene;
DOI:10.1021/jo050644v

Reference yield:

: 135582-87-5
(S)-methyl 3-(benzyloxycarbonylamino)-2-hydroxypropanoate

: 866007-04-7
(3S,4S)-3-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-2,5-dioxa-1,1-di(isopropyl)silolane

Guidance literature:: Multi-step reaction with 3 steps

1: 11 percent / B(C₆F₅)3 / toluene / 24 h / Heating

2: 78 percent / DIBAL / CH₂Cl₂ / 1 h / -78 °C

3: 91 percent / toluene-d8 / 30 h / 120 °C

With tris(pentafluorophenyl)borate; diisobutylaluminium hydride; In dichloromethane; ⁽²⁾H₈-toluene; toluene;
DOI:10.1021/jo050644v