Technology Process of 5,5'-(1,4-Phenylen)bis<2-(tert-butylthio)-1,3-dithiolylium-4-olat>
There total 6 articles about 5,5'-(1,4-Phenylen)bis<2-(tert-butylthio)-1,3-dithiolylium-4-olat> which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
trifluoroacetic anhydride;
In
diethyl ether; hexane;
at 0 ℃;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: conc. HCl / 1.) 12 h, room temp.; 2.) 2 h, 60-70 deg C
2: conc. HCl / 0.25 h
3: 1.) 63percent aqu. HBr; 2.) 80percent H2SO4 / 1.) 4 d, room temp.; 2.) 2 h, 120 deg C; 3.) 1 h, 100 deg C
4: 1.) KOH; 2.) Na2CO3 / 1.) H2O
5: 76 percent / trifluoroacetic anhydride / diethyl ether; hexane / 0 °C
With
hydrogenchloride; potassium hydroxide; sulfuric acid; hydrogen bromide; sodium carbonate; trifluoroacetic anhydride;
In
diethyl ether; hexane;
- Guidance literature:
-
Multi-step reaction with 6 steps
1: NaHSO3 / H2O / 4 h / 5 - 10 °C
2: conc. HCl / 1.) 12 h, room temp.; 2.) 2 h, 60-70 deg C
3: conc. HCl / 0.25 h
4: 1.) 63percent aqu. HBr; 2.) 80percent H2SO4 / 1.) 4 d, room temp.; 2.) 2 h, 120 deg C; 3.) 1 h, 100 deg C
5: 1.) KOH; 2.) Na2CO3 / 1.) H2O
6: 76 percent / trifluoroacetic anhydride / diethyl ether; hexane / 0 °C
With
hydrogenchloride; potassium hydroxide; sulfuric acid; hydrogen bromide; sodium carbonate; sodium hydrogensulfite; trifluoroacetic anhydride;
In
diethyl ether; hexane; water;
