[Mo₂Cp₂(μ-PCy₂)(μ-CO)₂]^-Na⁺

Base Information

• Chemical Name: [Mo₂Cp₂(μ-PCy₂)(μ-CO)₂]^-Na⁺
• CAS No.: 537683-65-1
• Molecular Formula: C₂₄H₃₂Mo₂O₂P*Na
• Molecular Weight: 598.36
• Mol file: 537683-65-1.mol

Synonyms:[Mo₂Cp₂(μ-PCy₂)(μ-CO)₂]^-Na⁺

Chemical Property of [Mo₂Cp₂(μ-PCy₂)(μ-CO)₂]^-Na⁺

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Mo₂Cp₂(μ-PCy₂)(μ-CO)₂]^-Na⁺

There total 1 articles about [Mo₂Cp₂(μ-PCy₂)(μ-CO)₂]^-Na⁺ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Mo2(μ-Cl)(η5-cyclopentadienyl)2(μ-dicyclohexylphosphide)(carbonyl)2] (537683-52-6) → [Mo2Cp2(μ-PCy2)(μ-CO)2]-Na+ (537683-65-1)

Guidance literature:

With sodium amalgam; In tetrahydrofuran; (N2, Schlenk) the soln. of complex in THF was stirred with an excess of sodium amalgam for ca. 15 min; not isolated;

DOI:10.1039/b909493h

Reference yield: 83.0%

[Mo2Cp2(μ-PCy2)(μ-CO)2]-Na+ (537683-65-1) + iodine (7553-56-2,12190-71-5,8031-47-8) → [Mo2Cp2(μ-I)(μ-PCy2)(μ-CO)]

Guidance literature:

In tetrahydrofuran; byproducts: KI; (N2, Schlenk) a THF soln. of complex was stirred with I2 for 1 min; the solvent was removed under vac., the residue was extd. with toluene, filtered, the solvent was removed, chromd. on alumina (activity IV), CH2Cl2-petroleum ether (1:3);

DOI:10.1039/b909493h

Reference yield: 62.0%

[Re(η5-C5H4Me)(CO)2(NO)]BF4 + [Mo2Cp2(μ-PCy2)(μ-CO)2]-Na+ (537683-65-1) → [Mo2ReCp2(η5-C5H4Me)(μ-N)(μ-O)(μ-PCy2)(CO)4]

Guidance literature:

In dichloromethane; at -20.16 ℃; for 0.75h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic3027489

upstream raw materials:

[Mo2(μ-Cl)(η5-cyclopentadienyl)2(μ-dicyclohexylphosphide)(carbonyl)2]