Technology Process of (C5H5)Fe(C5H4COC6H4OH)
There total 1 articles about (C5H5)Fe(C5H4COC6H4OH) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
boron tribromide;
In
dichloromethane;
under Ar atm. to soln. Fe complex in CH2Cl2 at 0°C BBr3 was addedand stirred overnight at room temp.; soln. was poured in mixt. water and ice and extd. with EtOAc, org. layerwas washed with water, dried over MgSO4 and concd. in vacuo, column chr omy. on silica (CH2Cl2), crystn. from ether-pentane; elem. anal.;
DOI:10.1039/b705030e
- Guidance literature:
-
With
titanium tetrachloride; zinc;
In
tetrahydrofuran;
under Ar atm. TiCl4 was added dropwise to suspn. Zn powder in THF at 0°C and heated at reflux for 2 h, soln. propionyl ferrocene and ferrocene-ketone in THF was added dropwise and refluxed for 2 h; react. mixt. was cooled to room temp. and stirred with water and CH2Cl2,acidified with HCl and decanted, org. layer was dried over MgSO4, concd . and chromd. on silica (CH2Cl2) + HPLC (MeCN-water 90:10); elem. anal.;
DOI:10.1039/b705030e
