indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide

Base Information

• Chemical Name: indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide
• CAS No.: 130669-46-4
• Molecular Formula: C₄₈H₂₄F₁₂InN₇
• Molecular Weight: 1041.57
• Mol file: 130669-46-4.mol

Synonyms:indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide

Chemical Property of indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide

There total 1 articles about indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

(C48H24N4F12)InCl (56398-54-0) → indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide (130669-46-4)

Guidance literature:

With NaN₃; In dichloromethane; stirring for 12 h at room temp.; filtration, recrystn. (toluene);

Reference yield: 87.0%

indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide (130669-46-4) + acrylonitrile (107-13-1,25014-41-9) → In(C20H8N4(C6H4CF3)4){N4C(CHCH2)} (143933-55-5)

Guidance literature:

In toluene; refluxing the In(III)porphyrin azide in toluene with 2 equiv of the nitrile under Ar, monitoring the disappearance of the azide band by IR; evapg., recrystn. (toluene/heptane); elem. anal.;

DOI:10.1039/DT9920001957

Reference yield: 58.0%

indium(III)(5,10,15,20-tetra-p-trifluoromethylphenylporphyrin) azide (130669-46-4) + acetonitrile (75-05-8,26809-02-9) → (C48H24N4F12)In{N4C(CH3)} (130669-42-0)

Guidance literature:

In toluene; reflux for about 4 h; evapn., recrystn. (toluene), elem. anal.;

upstream raw materials:

(C₄₈H₂₄N₄F₁₂)InCl

Downstream raw materials:

(C₄₈H₂₄N₄F₁₂)In{N₄C(CH₂CH₃)}

(C₄₈H₂₄N₄F₁₂)In{N₄C(C₆H₅)}

(C₄₈H₂₄N₄F₁₂)In{N₄C(CH₃)}

In(C₂₀H₈N₄(C₆H₄CF₃)4){N₄C(CHCHCN)}