methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

Base Information

Chemical Name:methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate
CAS No.:96149-11-0
Molecular Formula:C₂₀H₂₆O₅
Molecular Weight:346.423
Hs Code.:

Synonyms:methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

Suppliers and Price of methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

There total 2 articles about methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 96056-09-6
(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-1(S)-(hydroxymethyl)-2,9-dioxabicyclo<3.3.1>nonane

: 96149-11-0
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

Guidance literature:: Multi-step reaction with 2 steps

1: oxalyl chloride, DMSO / CH₂Cl₂ / 0.2 h / -60 °C

2: CH₂Cl₂ / 0.17 h / Ambient temperature

With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane;
DOI:10.1021/jo00212a041

Reference yield:

: (1S,4S,5R,6R,7S)-7-Benzyloxy-4,6-dimethyl-2,9-dioxa-bicyclo[3.3.1]nonane-1-carbaldehyde

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 96149-11-0
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

: 96056-10-9
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-trans-propenoate

Guidance literature:: In dichloromethane; for 0.166667h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;
DOI:10.1021/jo00212a041