difuran-2-yl(dimethyl)silane

Base Information

• Chemical Name: difuran-2-yl(dimethyl)silane
• CAS No.: 1578-44-5
• Molecular Formula: C10H12 O2 Si
• Molecular Weight: 192.2866
• Mol file: 1578-44-5.mol

Synonyms:Silane,di-2-furyldimethyl- (7CI,8CI); Di-2-furyldimethylsilane

Chemical Property of difuran-2-yl(dimethyl)silane

Chemical Property:

• Vapor Pressure: 0.319mmHg at 25°C
• Boiling Point: 207.7°C at 760 mmHg
• Flash Point: 79.4°C
• Density: 1.04g/cm³

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of difuran-2-yl(dimethyl)silane

There total 15 articles about difuran-2-yl(dimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-bromofuran (584-12-3) + dimethylsilicon dichloride (75-78-5,30107-43-8) → bis (2-furyl)dimethylsilane (1578-44-5)

Guidance literature:

With tetrabutylammomium bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; 2:1 substrate/Me₂SiCl₂ ratio, electrochemical conditions (Mg anode, 2.2 F_.mol^-1);

DOI:10.1016/S0022-328X(98)00853-5

Reference yield: 85.0%

furan (110-00-9) + dimethylsilicon dichloride (75-78-5,30107-43-8) → bis (2-furyl)dimethylsilane (1578-44-5)

Guidance literature:

furan; With n-butyllithium; In hexane; for 1h; Heating;

dimethylsilicon dichloride; In hexane; at 20 ℃;

DOI:10.1515/znb-2000-1005

Reference yield: 75.0%

2,5-dibromofuran (32460-00-7) + dimethylsilicon dichloride (75-78-5,30107-43-8) → bis (2-furyl)dimethylsilane (1578-44-5)

Guidance literature:

With tetrabutylammomium bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; electrochemical conditions (Mg anode, 2.2 F_.mol^-1);

DOI:10.1016/S0022-328X(98)00853-5

upstream raw materials:

2-lithiofuran

bis-2-(5,6-dihydro-4H-pyranyl)dimethylsilane

[2-(4,5-dihydrofuryl)]dimethylsilane

Bis-(4,5-dihydro-furan-2-yl)-dimethyl-silane

Downstream raw materials:

<2-(4,5-dihydrofuryl)>dimethylphenylsilane