5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine

Base Information

• Chemical Name: 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine
• CAS No.: 1059193-41-7
• Molecular Formula: C₄₂H₄₄N₂O₂Si₂
• Molecular Weight: 664.995
• Mol file: 1059193-41-7.mol

Synonyms:5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine

Chemical Property of 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine

There total 2 articles about 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-[ethoxydi(prop-2-enyl)silyl]iodobenzene (959419-50-2) + 5,5'-diethynyl-2,2'-bipyridyl (162318-26-5) → 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine (1059193-41-7)

Guidance literature:

With diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In tetrahydrofuran; at 75 ℃; for 39h;

Reference yield: 84.0%

5,5'-dibromo-2,2'-dipyridyl (15862-18-7) + 1-(diallylethoxysilyl)-4-ethynylbenzene (1059193-35-9) → 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine (1059193-41-7)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; diisopropylamine; In benzene; for 40h; Inert atmosphere; Reflux;

DOI:10.1002/chem.201102492

Reference yield: 75.0%

cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3) + 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine (1059193-41-7) → C62H60N6O2RuSi2(2+)*2F6P(1-)

Guidance literature:

cis-dichlorobis(2,2′-bipyridine)ruthenium(II); 5,5'-bis[4-(diallylethoxysilyl)phenylethynyl]-2,2'-bipyridine; In ethanol; water; for 20h; Heating / reflux;

With ammonium hexafluorophosphate; In ethanol; water;

upstream raw materials:

4-[ethoxydi(prop-2-enyl)silyl]iodobenzene

5,5'-diethynyl-2,2'-bipyridyl

5,5'-dibromo-2,2'-dipyridyl

1-(diallylethoxysilyl)-4-ethynylbenzene