C₄₆H₆₈O₆Si₂

Base Information

Chemical Name:C₄₆H₆₈O₆Si₂
CAS No.:1261152-27-5
Molecular Formula:C₄₆H₆₈O₆Si₂
Molecular Weight:773.213
Hs Code.:

C<sub>46</sub>H<sub>68</sub>O<sub>6</sub>Si<sub>2</sub>

Synonyms:C₄₆H₆₈O₆Si₂

Suppliers and Price of C₄₆H₆₈O₆Si₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₄₆H₆₈O₆Si₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₄₆H₆₈O₆Si₂

There total 17 articles about C₄₆H₆₈O₆Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₄₄H₆₄O₇Si₂

: 1530-32-1
ethyltriphenylphosphonium bromide

: 1261152-27-5
C₄₆H₆₈O₆Si₂

Guidance literature:: ethyltriphenylphosphonium bromide; With sodium hexamethyldisilazane; In tetrahydrofuran; toluene; at 0 ℃; for 0.166667h; Inert atmosphere;

C₄₄H₆₄O₇Si₂; In tetrahydrofuran; toluene; at 0 ℃; for 0.333333h; Inert atmosphere;
DOI:10.1021/ja109533y

Reference yield:

: 1261152-38-8
C₄₁H₆₄O₅Si₃

: 1261152-27-5
C₄₆H₆₈O₆Si₂

Guidance literature:: Multi-step reaction with 15 steps

1.1: 20 % Pd(OH)2/C; hydrogen / ethanol / 18 h / 25 °C / Inert atmosphere

2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.17 h / -78 °C / Inert atmosphere

2.2: 1 h / -78 °C / Inert atmosphere

2.3: 2 h / -78 - 0 °C / Inert atmosphere

3.1: dichloromethane / 1.5 h / 25 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine / dichloromethane / 14 h / 0 °C / Inert atmosphere

5.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

5.2: 16 h / 25 °C / Inert atmosphere

6.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 1 h / -25 °C / Inert atmosphere; Molecular sieve

6.2: 17 h / -20 °C / Inert atmosphere; Molecular sieve

7.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

8.1: dichloromethane / 14 h / 20 °C / Inert atmosphere

9.1: tetrabutyl ammonium fluoride / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

10.1: pyridinium p-toluenesulfonate / dichloromethane / 25 - 40 °C / Inert atmosphere

11.1: lanthanum(lll) triflate / toluene / 6 h / 25 °C / Inert atmosphere

12.1: sodium tetrahydroborate; nickel (II) chloride hexahydrate / ethanol / 0 °C / Inert atmosphere

13.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 25 °C / Inert atmosphere

14.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

15.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

15.2: 0.33 h / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; sodium tetrahydroborate; lithium aluminium tetrahydride; oxalyl dichloride; nickel (II) chloride hexahydrate; diethyl (2S,3S)-tartrate; 20 % Pd(OH)2/C; tetrabutyl ammonium fluoride; hydrogen; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; lanthanum(lll) triflate; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; toluene; 2.1: Swern oxidation / 2.2: Swern oxidation / 2.3: Swern oxidation / 3.1: Wittig reaction / 6.1: Sharpless epoxidation / 6.2: Sharpless epoxidation / 7.1: Parikh-Doering oxidation / 8.1: Wittig reaction / 14.1: Parikh-Doering oxidation / 15.1: Wittig reaction / 15.2: Wittig reaction;
DOI:10.1021/ja109533y

Reference yield:

: 1261152-23-1
C₃₁H₄₈O₅Si₂

: 1261152-27-5
C₄₆H₆₈O₆Si₂

Guidance literature:: Multi-step reaction with 13 steps

1.1: dichloromethane / 1.5 h / 25 °C / Inert atmosphere

2.1: 2,6-dimethylpyridine / dichloromethane / 14 h / 0 °C / Inert atmosphere

3.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

3.2: 16 h / 25 °C / Inert atmosphere

4.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 1 h / -25 °C / Inert atmosphere; Molecular sieve

4.2: 17 h / -20 °C / Inert atmosphere; Molecular sieve

5.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

6.1: dichloromethane / 14 h / 20 °C / Inert atmosphere

7.1: tetrabutyl ammonium fluoride / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

8.1: pyridinium p-toluenesulfonate / dichloromethane / 25 - 40 °C / Inert atmosphere

9.1: lanthanum(lll) triflate / toluene / 6 h / 25 °C / Inert atmosphere

10.1: sodium tetrahydroborate; nickel (II) chloride hexahydrate / ethanol / 0 °C / Inert atmosphere

11.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 25 °C / Inert atmosphere

12.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

13.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

13.2: 0.33 h / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; sodium tetrahydroborate; lithium aluminium tetrahydride; nickel (II) chloride hexahydrate; diethyl (2S,3S)-tartrate; tetrabutyl ammonium fluoride; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; lanthanum(lll) triflate; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; toluene; 1.1: Wittig reaction / 4.1: Sharpless epoxidation / 4.2: Sharpless epoxidation / 5.1: Parikh-Doering oxidation / 6.1: Wittig reaction / 12.1: Parikh-Doering oxidation / 13.1: Wittig reaction / 13.2: Wittig reaction;
DOI:10.1021/ja109533y