(2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

Base Information

Chemical Name:(2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol
CAS No.:209899-68-3
Molecular Formula:C₅₈H₉₇NO₆
Molecular Weight:904.411
Hs Code.:

Synonyms:(2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

Suppliers and Price of (2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

There total 15 articles about (2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 182362-51-2
hexacosanoic acid (2,3-dihydroxy-1-hydroxymethyl-heptadecyl) amide

: 209899-68-3
(2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

Guidance literature:: Multi-step reaction with 3 steps

1: DMAP; pyridine / 40 °C

2: DMAP; pyridine / 40 °C

3: 92 percent / p-toluenesulfonic acid; MeOH

With pyridine; methanol; dmap; toluene-4-sulfonic acid;
DOI:10.1016/j.bmcl.2006.01.040

Reference yield:

: 765-09-3
1-bromotridecane

: 209899-68-3
(2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

Guidance literature:: Multi-step reaction with 11 steps

1: 12 h / 150 °C

2: 1.) nBuLi / 1.) hexane, THF, -10 deg C, 30 min, 2.) hexane, THF, RT, 16 h

3: H₂ / 10percent Pd/C / tetrahydrofuran / 16 h

4: pyridine / 1.5 h / 20 °C

5: NaN₃ / dimethylformamide / 16 h / 100 °C

6: H₂ / 10percent Pd/C / tetrahydrofuran / 16 h / Ambient temperature

7: 2-chloro-1-methylpyridinium iodide, n-tributylamine / CH₂Cl₂ / 2 h / Heating

8: H₂ / Pd / tetrahydrofuran; propan-1-ol / 16 h / 40 °C

9: pyridine, 4-(dimethylamino)pyridine / 3 h / 40 °C

10: pyridine, 4-(dimethylamino)pyridine / 12 h / Ambient temperature

11: pTsOH*H₂O / CH₂Cl₂; methanol / 2 h / Ambient temperature

With pyridine; dmap; n-butyllithium; sodium azide; tributyl-amine; 2-chloro-1-methyl-pyridinium iodide; hydrogen; toluene-4-sulfonic acid; palladium on activated charcoal; palladium; In tetrahydrofuran; methanol; propan-1-ol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm00012a018

Reference yield:

: 20672-66-6,40246-26-2,84926-76-1,114179-79-2,115184-49-1
3,4,5-tri-O-benzyl-D-galactopyranose

: 209899-68-3
(2S,3S,4R)-2-(N-hexacosanoylamino)-3,4-di-O-benzoyl-1,3,4-octadecanetriol

Guidance literature:: Multi-step reaction with 11 steps

1: NaIO₄ / ethanol; H₂O / 16 h / -5 - 20 °C

2: 1.) nBuLi / 1.) hexane, THF, -10 deg C, 30 min, 2.) hexane, THF, RT, 16 h

3: H₂ / 10percent Pd/C / tetrahydrofuran / 16 h

4: pyridine / 1.5 h / 20 °C

5: NaN₃ / dimethylformamide / 16 h / 100 °C

6: H₂ / 10percent Pd/C / tetrahydrofuran / 16 h / Ambient temperature

7: 2-chloro-1-methylpyridinium iodide, n-tributylamine / CH₂Cl₂ / 2 h / Heating

8: H₂ / Pd / tetrahydrofuran; propan-1-ol / 16 h / 40 °C

9: pyridine, 4-(dimethylamino)pyridine / 3 h / 40 °C

10: pyridine, 4-(dimethylamino)pyridine / 12 h / Ambient temperature

11: pTsOH*H₂O / CH₂Cl₂; methanol / 2 h / Ambient temperature

With pyridine; dmap; sodium periodate; n-butyllithium; sodium azide; tributyl-amine; 2-chloro-1-methyl-pyridinium iodide; hydrogen; toluene-4-sulfonic acid; palladium on activated charcoal; palladium; In tetrahydrofuran; methanol; propan-1-ol; ethanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jm00012a018