methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

Base Information

Chemical Name:methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside
CAS No.:1346417-99-9
Molecular Formula:C₂₂H₃₄O₇Si
Molecular Weight:438.593
Hs Code.:

Synonyms:methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

Suppliers and Price of methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

There total 5 articles about methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1346417-98-8
methyl 2-O-acetyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-ribohexopyranoside

: 65-85-0,8013-63-6
benzoic acid

: 1346417-99-9
methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In toluene; at 24 ℃; for 0.833333h; Inert atmosphere;
DOI:10.1021/jo201673w

Reference yield:

: 102191-92-4
tert-butyldimethylsiloxyacetaldehyde

: 1346417-99-9
methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: C₂₇H₂₉NO₂^(2-)*ClCr⁽²⁺⁾ / 17 h / 0 - 24 °C / Molecular sieve; Inert atmosphere

2: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 16 h / 24 °C

3: pyridine; dmap / dichloromethane / 0.83 h / 24 °C / Inert atmosphere

4: di-isopropyl azodicarboxylate; triphenylphosphine / toluene / 0.83 h / 24 °C / Inert atmosphere

With pyridine; dmap; osmium(VIII) oxide; di-isopropyl azodicarboxylate; C₂₇H₂₉NO₂^(2-)*ClCr⁽²⁺⁾; 4-methylmorpholine N-oxide; triphenylphosphine; In dichloromethane; water; acetone; toluene; 4: Mitsunobu reaction;
DOI:10.1021/jo201673w

Reference yield:

: (2R,6S)-6-(tert-butyldimethylsilyloxymethyl)-2-methoxy-2,5-dihydropyran

: 1346417-99-9
methyl 2-O-acetyl-3-O-benzoyl-6-O-(tert-butyldimethylsilyl)-4-deoxy-β-D-xylohexopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 16 h / 24 °C

2: pyridine; dmap / dichloromethane / 0.83 h / 24 °C / Inert atmosphere

3: di-isopropyl azodicarboxylate; triphenylphosphine / toluene / 0.83 h / 24 °C / Inert atmosphere

With pyridine; dmap; osmium(VIII) oxide; di-isopropyl azodicarboxylate; 4-methylmorpholine N-oxide; triphenylphosphine; In dichloromethane; water; acetone; toluene; 3: Mitsunobu reaction;
DOI:10.1021/jo201673w