(+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one

Base Information

Chemical Name:(+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one
CAS No.:960294-63-7
Molecular Formula:C₂₉H₄₆O₈Si
Molecular Weight:550.765
Hs Code.:

(+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one

Synonyms:(+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one

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Chemical Property of (+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one

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Technology Process of (+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one

There total 1 articles about (+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 960294-72-8
C₂₉H₄₄O₆Si

: 960294-63-7
(+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one

Guidance literature:: C₂₉H₄₄O₆Si; With pyridine; osmium(VIII) oxide; In tetrahydrofuran; at 20 ℃; for 0.583333h;

With hydrogen sulfide; In tetrahydrofuran; at 0 ℃; Further stages.;
DOI:10.1002/anie.200702056

Reference yield: 79.0%

: 960294-63-7
(+)-(1S,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-1-((1R,2R)-1,2-dihydroxy-4,4-dimethylcyclopentyl)-6-hydroxy-3-oxa-bicyclo[4.2.0]octan-4-one

: 960294-64-8
(+)-(1R,5S,6S,7R)-7-(4-methoxybenzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)-6-hydroxy-1-((R)-1-hydroxy-4,4-dimethyl-2-oxocyclopentyl)-3-oxa-bicyclo[4.2.0]octan-4-one

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; for 1h; cooling;
DOI:10.1002/anie.200702056